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[μ-1,1'-(丁烷-1,4-二基)二-1H-苯并咪唑-κN:N]双-{[N,N'-双(羧甲基)乙二胺-N,N'-二乙酸根合-κO,O',O'',N,N']汞(II)}甲醇溶剂化物

[μ-1,1'-(Butane-1,4-di-yl)di-1H-benz-imidazole-κN:N]bis-{[N,N'-bis(car-boxy-meth-yl)ethyl-enediamine-N,N'-di-acetato-κO,O',O'',N,N']mercury(II)} methanol disolvate.

作者信息

Zhu Xue-Wen, Xiao Bo, Yin Zhi-Gang, Qian Heng-Yu, Li Gang-Sen

机构信息

Key Laboratory of Surface and Interface Science of Henan, School of Materials & Chemical Engineering, Zhengzhou University of Light Industry, Zhengzhou 450002, People's Republic of China.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2009 Jul 11;65(Pt 8):m912. doi: 10.1107/S1600536809026221.

DOI:10.1107/S1600536809026221
PMID:21583370
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2977252/
Abstract

The binuclear title complex, [Hg(2)(C(10)H(14)N(2)O(8))(2)(C(18)H(18)N(4))]·2CH(3)OH, lies on an inversion center with the unique Hg(II) ion coordinated in a disorted octa-hedral environment with one Hg-N bond significantly shorter than the other two. In the crystal structure, inter-molecular O-H⋯O hydrogen bonds link complex and solvent mol-ecules into a three-dimensional network.

摘要

双核标题配合物[Hg₂(C₁₀H₁₄N₂O₈)₂(C₁₈H₁₈N₄)]·2CH₃OH位于一个对称中心上，独特的Hg(II)离子在一个扭曲的八面体环境中配位，其中一个Hg-N键明显短于另外两个。在晶体结构中，分子间的O-H⋯O氢键将配合物和溶剂分子连接成一个三维网络。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5433/2977252/a66ec8dddd58/e-65-0m912-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5433/2977252/535e1a3cc31a/e-65-0m912-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5433/2977252/a66ec8dddd58/e-65-0m912-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5433/2977252/535e1a3cc31a/e-65-0m912-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5433/2977252/a66ec8dddd58/e-65-0m912-fig2.jpg

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