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双（1-苄基-3-甲基咪唑鎓-κC）汞（II）双（六氟磷酸盐）

Bis(1-benzyl-3-methyl-imidazolium-κC)mercury(II) bis-(hexa-fluoridophosphate).

作者信息

Haque Rosenani A, Salman Abbas Washeel, Hemamalini Madhukar, Fun Hoong-Kun

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2011 Sep 1;67(Pt 9):m1242-3. doi: 10.1107/S1600536811032235. Epub 2011 Aug 17.

DOI:10.1107/S1600536811032235
PMID:22064754
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3200814/
Abstract

The asymmetric unit of the title complex, Hg(C(11)H(12)N(2))(2)(2), consists of one bis-(1-benzyl-3-methyl-imidazolium)mercury(II) cation, one half of the cation and an additional Hg(II) atom, which lies on an inversion centre, and three hexa-fluorido-phosphate anions. The Hg(II) atoms exist in a linear coordination geometry [C-Hg-C = 178.9 (2) and 180°] formed by two carbene C atoms from the imidazole rings. In the crystal, the cations and anions are connected via C-H⋯F hydrogen bonds, forming a three-dimensional network.

摘要

标题配合物Hg(C₁₁H₁₂N₂)₂₂的不对称单元由一个双-(1-苄基-3-甲基-咪唑鎓)汞(II)阳离子、阳离子的一半以及位于对称中心的一个额外Hg(II)原子和三个六氟磷酸根阴离子组成。Hg(II)原子以由咪唑环上的两个卡宾C原子形成的线性配位几何构型存在[C-Hg-C = 178.9 (2)°和180°]。在晶体中，阳离子和阴离子通过C-H⋯F氢键相连，形成三维网络。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4b61/3200814/4f10753a7830/e-67-m1242-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4b61/3200814/5c48a4c4eade/e-67-m1242-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4b61/3200814/4f10753a7830/e-67-m1242-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4b61/3200814/5c48a4c4eade/e-67-m1242-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4b61/3200814/4f10753a7830/e-67-m1242-fig2.jpg

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