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（E）-4-氯-N-[(E)-2-甲基-3-苯基-亚烯丙基]苯胺

(E)-4-Chloro-N-[(E)-2-methyl-3-phenyl-allyl-idene]aniline.

作者信息

Khalaji Aliakbar D, Simpson Jim

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2009 Jan 23;65(Pt 2):o362. doi: 10.1107/S1600536809001871.

DOI:10.1107/S1600536809001871
PMID:21581960
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2968393/
Abstract

The title Schiff base compound, C(16)H(14)ClN, adopts E configurations with respect to both the C=C and C=N bonds. The dihedral angle between the two aromatic rings is 53.27 (4)°, while the plane through the C=C-C=N system is inclined at 9.06 (8)° to the benzene ring and 44.92 (5)° to the chloro-benzene ring. In the crystal structure, weak C-H⋯Cl and C-H⋯N hydrogen bonds stack the mol-ecules down the a axis.

摘要

席夫碱化合物C(16)H(14)ClN的C=C键和C=N键均呈E构型。两个芳香环之间的二面角为53.27 (4)°，而通过C=C-C=N体系的平面相对于苯环倾斜9.06 (8)°，相对于氯苯环倾斜44.92 (5)°。在晶体结构中，弱的C-H⋯Cl和C-H⋯N氢键使分子沿a轴堆积。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8dca/2968393/38cf8bcfe9e0/e-65-0o362-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8dca/2968393/76bd60afb5d9/e-65-0o362-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8dca/2968393/38cf8bcfe9e0/e-65-0o362-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8dca/2968393/76bd60afb5d9/e-65-0o362-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8dca/2968393/38cf8bcfe9e0/e-65-0o362-fig2.jpg

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