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硝酸三（三苯基膦）铜（I）甲醇溶剂合物

Nitratotris(triphenyl-phosphine)copper(I) methanol solvate.

作者信息

Steyl Gideon

机构信息

Department of Chemistry, University of the Free State, Bloemfontein 9300, South Africa.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2009 Feb 13;65(Pt 3):m272. doi: 10.1107/S1600536809004620.

DOI:10.1107/S1600536809004620
PMID:21582060
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2968546/
Abstract

The title compound, [Cu(NO(3))(C(18)H(15)P)(3)]·CH(3)OH, is a methanol solvate derivative of nitratotris(triphenyl-phos-phine)copper(I). The complex crystallizes with three triphenyl-phosphine ligands coordinated to the copper centre, with an O-H⋯O hydrogen bond observed between the nitrate ligand and the methanol solvent mol-ecule. The coordination around the Cu(I) centre is distorted tetrahedral.

摘要

标题化合物[Cu(NO₃)(C₁₈H₁₅P)₃]·CH₃OH是硝酸三（三苯基膦）铜（I）的甲醇溶剂化物衍生物。该配合物结晶时，三个三苯基膦配体与铜中心配位，在硝酸根配体和甲醇溶剂分子之间观察到O—H⋯O氢键。Cu（I）中心周围的配位呈扭曲的四面体构型。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/90e9/2968546/85c225abde4e/e-65-0m272-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/90e9/2968546/85c225abde4e/e-65-0m272-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/90e9/2968546/85c225abde4e/e-65-0m272-fig1.jpg

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