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{4-Bromo-2-[(2-morpholinoeth-yl)imino-meth-yl]phenolato}iodido(methanol)zinc(II).

作者信息

Han Cheng-Li

机构信息

College of Chemistry and Chemical Engineering, Qiqihar University, Qiqihar 161006, People's Republic of China.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2009 Mar 19;65(Pt 4):m418. doi: 10.1107/S1600536809009234.

Abstract

The title compound, [Zn(C(13)H(16)BrN(2)O(2))I(CH(3)OH)], is a new mononuclear zinc(II) complex synthesized by the reaction of equimolar quanti-ties of 5-bromo-salicylaldehyde, 2-morpholinoethyl-amine and ZnI(2) in methanol. The Zn atom is four-coordinate in a distorted tetra-hedral geometry, binding to a phenolate O and an imine N atom of the Schiff base ligand, the O atom of a methanol mol-ecule and one I(-) anion. In the crystal structure, adjacent mol-ecules are linked through inter-molecular O-H⋯O hydrogen bonds, forming centrosymmetric dimers.

摘要
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/07b5/2968908/5be653986dc9/e-65-0m418-fig1.jpg

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