Boeckmann Jan, Jess Inke, Näther Christian
Institut für Anorganische Chemie, Christian-Albrechts-Universität Kiel, Max-Eyth Strasse 2, D-24098 Kiel, Germany.
Acta Crystallogr Sect E Struct Rep Online. 2009 Mar 25;65(Pt 4):m421. doi: 10.1107/S1600536809009301.
In the crystal structure of the title compound, Mn(C(12)H(6)O(4))(C(10)H(8)N(2)), the Mn atoms are each coordinated by four O atoms of naphthalene-1,4-dicarboxyl-ate anions and two N atoms of two symmetry-related 4,4'-bipyridine ligands within a strongly distorted octa-hedra. Two of the O atoms originate from one naphthalene-1,4-dicarboxyl-ate anion, whereas the remaining two O atoms derive from two symmetry-equivalent naphthalene-1,4-dicarboxyl-ate anions. Two Mn atoms are connected via the anions into dimers, which are further linked by the anions and the N-donor ligands into a three-dimensional coordination network.
在标题化合物[Mn(C₁₂H₆O₄)(C₁₀H₈N₂)]ₙ的晶体结构中，锰原子分别由萘-1,4-二羧酸根阴离子的四个氧原子和两个对称相关的4,4'-联吡啶配体的两个氮原子在一个严重扭曲的八面体中配位。其中两个氧原子来自一个萘-1,4-二羧酸根阴离子，而其余两个氧原子来自两个对称等效的萘-1,4-二羧酸根阴离子。两个锰原子通过阴离子连接成二聚体，这些二聚体再通过阴离子和氮供体配体进一步连接成三维配位网络。
