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顺式-双[2-(1,3-苯并噻唑-2-基)-1-(4-氟苯基)乙烯基](戊烷-2,4-二酮-κO,O')铱(III)

cis-Bis[2-(1,3-benzothia-zol-2-yl)-1-(4-fluoro-phen-yl)ethen-yl](pentane-2,4-dionato-κO,O')iridium(III).

作者信息

Xiao Guo-Yong, Lei Peng, Chi Hai-Jun, Hu Zhi-Zhi, Li Xiao

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2009 Mar 25;65(Pt 4):m440. doi: 10.1107/S1600536809010204.

DOI:10.1107/S1600536809010204
PMID:21582377
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2968936/
Abstract

In the title compound, [Ir(C(15)H(9)FNS)(2)(C(5)H(7)O(2))], the Ir atom is hexa-coordinated by three chelating ligands, with two cyclo-metalated 2-(1,3-benzothia-zol-2-yl)-1-(4-fluoro-phen-yl)ethenyl ligands showing N,C-bidentate coordination and an O,O'-bidenate pentane-2,4-dionate anion, thereby forming a distorted octa-hedral enviroment.

摘要

在标题化合物[Ir(C₁₅H₉FNS)₂(C₅H₇O₂)]中，Ir原子由三个螯合配体六配位，其中两个环金属化的2-(1,3-苯并噻唑-2-基)-1-(4-氟苯基)乙烯基配体呈现N,C-双齿配位，还有一个O,O'-双齿的戊烷-2,4-二酮阴离子，从而形成一个扭曲的八面体环境。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/976b/2968936/b126609780de/e-65-0m440-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/976b/2968936/b126609780de/e-65-0m440-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/976b/2968936/b126609780de/e-65-0m440-fig1.jpg

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本文引用的文献

1
[2-(Phenyl-diazen-yl)pyrrolato]bis(2-pyridylphen-yl)iridium(III).[2-(苯基重氮基)吡咯根合]双(2-吡啶基苯基)铱(III)
Acta Crystallogr Sect E Struct Rep Online. 2008 Feb 20;64(Pt 3):m490. doi: 10.1107/S1600536808004443.
2
A short history of SHELX.SHELX简史。
Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22. doi: 10.1107/S0108767307043930. Epub 2007 Dec 21.