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双[2-(1,3-苯并噻唑-2-基)苯基-κ(2)C(1),N][1,3-双(4-溴苯基)丙烷-1,3-二酮-κ(2)O,O']铱(III)

Bis[2-(1,3-benzo-thia-zol-2-yl)phenyl-κ(2) C (1),N][1,3-bis-(4-bromo-phen-yl)propane-1,3-dionato-κ(2) O,O']iridium(III).

作者信息

Kim Young-Inn, Yun Seong-Jae, Kang Sung Kwon

机构信息

Department of Chemistry Education and Interdisciplinary Program of Advanced Information and Display Materials, Pusan National University, Busan 609-735, Republic of Korea.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2013 Jul 10;69(Pt 8):m443. doi: 10.1107/S1600536813018394. eCollection 2013.

DOI:10.1107/S1600536813018394
PMID:24109271
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3793684/
Abstract

The title complex, [Ir(C15H9Br2O2)(C13H8NS)2], lies about a crystallographic twofold rotation axis passing through the Ir(III) atom and the central C atom of the bis-(bromo-phen-yl)propane-1,3-dionate ligand. The Ir(III) atom adopts a distorted octa-hedral geometry coordinated by two N atoms in the axial positions, and two C and two O atoms in the equatorial plane. The dihedral angle between the two thia-zole ring systems in the complex is 77.45 (10)°.

摘要

标题配合物[Ir(C₁₅H₉Br₂O₂)(C₁₃H₈NS)₂]位于一个通过Ir(III)原子和双(溴苯基)丙烷 - 1,3 - 二酮配体的中心C原子的晶体学二重旋转轴上。Ir(III)原子采用扭曲的八面体几何构型，轴向位置由两个N原子配位，赤道平面由两个C原子和两个O原子配位。配合物中两个噻唑环系统之间的二面角为77.45 (10)°。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4a86/3793684/336b6ce34a06/e-69-0m443-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4a86/3793684/336b6ce34a06/e-69-0m443-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4a86/3793684/336b6ce34a06/e-69-0m443-fig1.jpg

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本文引用的文献

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Chemphyschem. 2008 Mar 14;9(4):634-40. doi: 10.1002/cphc.200700648.
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Iridium(III) complexes with orthometalated quinoxaline ligands: subtle tuning of emission to the saturated red color.含邻位金属化喹喔啉配体的铱(III)配合物：将发射微调至饱和红色。
Inorg Chem. 2005 Mar 7;44(5):1344-53. doi: 10.1021/ic0489443.
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Homoleptic cyclometalated iridium complexes with highly efficient red phosphorescence and application to organic light-emitting diode.
具有高效红色磷光的均配环金属化铱配合物及其在有机发光二极管中的应用
J Am Chem Soc. 2003 Oct 22;125(42):12971-9. doi: 10.1021/ja034732d.