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{μ-1,3-Bis[(3,5-dimethyl-pyrazol-1-yl)meth-yl]benzene-κN:N}di-μ-chlorido-bis-[chloridopalladium(II)] toluene solvate.

作者信息

Omondi Bernard, Budhai Asheena, Darkwa James

机构信息

Department of Chemistry, University of Johannesburg, PO Box 524, Auckland Park, 2006 Johannesburg, South Africa.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2009 Mar 25;65(Pt 4):m446. doi: 10.1107/S1600536809010629.

Abstract

In the title complex, [Pd(2)Cl(4)(C(18)H(22)N(4))]·C(7)H(8), each of the two four-coordinated Pd(II) atoms is in a slightly distorted square-planar geometry, defined by one N atom from the ligand, two bridging Cl atoms and one terminal Cl atom. Inter-molecular C-H⋯π inter-actions between the pyrazole ring H atom and the toluene ring stabilize the crystal structure.

摘要
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/819c/2969090/def80b9369ff/e-65-0m446-fig1.jpg

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