{μ-1,3-双[(3,5-二甲基-吡唑-1-基)甲基]苯-κN:N}二-μ-氯代-双[氯化钯(II)]甲苯溶剂合物
{μ-1,3-Bis[(3,5-dimethyl-pyrazol-1-yl)meth-yl]benzene-κN:N}di-μ-chlorido-bis-[chloridopalladium(II)] toluene solvate.
作者信息
Omondi Bernard, Budhai Asheena, Darkwa James
机构信息
Department of Chemistry, University of Johannesburg, PO Box 524, Auckland Park, 2006 Johannesburg, South Africa.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2009 Mar 25;65(Pt 4):m446. doi: 10.1107/S1600536809010629.
In the title complex, [Pd(2)Cl(4)(C(18)H(22)N(4))]·C(7)H(8), each of the two four-coordinated Pd(II) atoms is in a slightly distorted square-planar geometry, defined by one N atom from the ligand, two bridging Cl atoms and one terminal Cl atom. Inter-molecular C-H⋯π inter-actions between the pyrazole ring H atom and the toluene ring stabilize the crystal structure.
在标题配合物[Pd₂Cl₄(C₁₈H₂₂N₄)]·C₇H₈中，两个四配位的Pd(II)原子均处于略微扭曲的平面正方形几何构型，由来自配体的一个N原子、两个桥连Cl原子和一个端基Cl原子确定。吡唑环H原子与甲苯环之间的分子间C-H⋯π相互作用使晶体结构得以稳定。
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