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（E）-N'-（3-氟-亚苄基）-2-羟基-苯甲酰肼

(E)-N'-(3-Fluoro-benzyl-idene)-2-hydroxy-benzohydrazide.

作者信息

Xu Hua-Jie, Sheng Liang-Quan, Liu Zhao-Di, Shao Si-Chang

机构信息

Department of Chemistry, Fuyang Normal College, Fuyang Anhui 236041, People's Republic of China.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2009 Mar 6;65(Pt 4):o666. doi: 10.1107/S1600536809006941.

DOI:10.1107/S1600536809006941
PMID:21582410
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2968967/
Abstract

The title compound, C(14)H(11)FN(2)O(2), adopts an E or trans configuration with respect to the C=N bond. An intra-molecular N-H⋯O hydrogen bond contributes to the relatively planarity of the mol-ecular conformation; the two benzene rings are inclined to one another by 12.5 (2)°. In the crystal structure, inter-molecular O-H⋯O hydrogen bonds link the mol-ecules into chains running parallel to the c axis.

摘要

标题化合物C(14)H(11)FN(2)O(2)相对于C=N键采取E或反式构型。分子内N-H⋯O氢键有助于分子构象的相对平面性；两个苯环彼此倾斜12.5 (2)°。在晶体结构中，分子间O-H⋯O氢键将分子连接成平行于c轴的链。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f12f/2968967/0360c622b121/e-65-0o666-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f12f/2968967/7d0192fb495b/e-65-0o666-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f12f/2968967/0360c622b121/e-65-0o666-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f12f/2968967/7d0192fb495b/e-65-0o666-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f12f/2968967/0360c622b121/e-65-0o666-fig2.jpg

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