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2-[(3,5-二叔丁基-4-羟基苄基)硫基]-N'-异丙叉乙酰肼

2-[(3,5-Di-tert-butyl-4-hydroxy-benz-yl)-sulfan-yl]-N'-isopropyl-ideneaceto-hydrazide.

作者信息

Yehye Wagee A, Ariffin Azhar, Ng Seik Weng

机构信息

Department of Chemistry, University of Malaya, 50603 Kuala Lumpur, Malaysia.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2009 Mar 11;65(Pt 4):o730. doi: 10.1107/S1600536809007843.

DOI:10.1107/S1600536809007843
PMID:21582464
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2968854/
Abstract

The title compound, C(20)H(32)N(2)O(2)S, the condensation product of a thio-acetohydrazine and acetone, has a two-coordinate S atom and the angle at this atom is 100.7 (1)°. The (CH(3))C=N-NH-C(O)- substituent engages in N-H⋯O hydrogen-bonding inter-actions with the substituent of an adjacent mol-ecule across a center of inversion, generating a dimeric structure.

摘要

标题化合物C(20)H(32)N(2)O(2)S是硫代乙酰肼与丙酮的缩合产物，具有一个两配位的S原子，该原子处的角度为100.7 (1)°。(CH(3))C=N-NH-C(O)-取代基通过一个反演中心与相邻分子的取代基进行N-H⋯O氢键相互作用，形成二聚体结构。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/366b/2968854/91a54a408a7a/e-65-0o730-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/366b/2968854/91a54a408a7a/e-65-0o730-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/366b/2968854/91a54a408a7a/e-65-0o730-fig1.jpg

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