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链状聚[[三苯基锡(IV)]-μ-2-[(3,5-二叔丁基-4-羟基苄基)硫烷基]乙酸根-κO:O']

catena-Poly[[triphenyl-tin(IV)]-μ-2-[(3,5-di-tert-butyl-4-hydroxy-benz-yl)sulfan-yl]acetato-κO:O'].

作者信息

Lee See Mun, Lo Kong Mun, Mohd Ali Hapipah, Robinson Ward T

机构信息

Department of Chemistry, University of Malaya, 50603 Kuala Lumpur, Malaysia.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2009 Jun 20;65(Pt 7):m808. doi: 10.1107/S1600536809023150.

DOI:10.1107/S1600536809023150
PMID:21582732
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2969233/
Abstract

The title compound, Sn(C(6)H(5))(3)(C(17)H(25)O(3)S), comprises two symmetry-independent five-coordinated triphenyl-tin mol-ecules which are linked by carboxyl-ate bridges into a polymeric chain. The Sn(IV) atom is in a distorted trans-C(3)SnO(2) trigonal-bipyramidal geometry. The presence of two bulky tert-butyl groups on the benzene ring prevents any hydrogen-bonding inter-actions involving the hydroxyl substituents.

摘要

标题化合物[Sn(C₆H₅)₃(C₁₇H₂₅O₃S)]ₙ由两个对称独立的五配位三苯基锡分子组成，这些分子通过羧酸盐桥连接成一条聚合物链。Sn(IV)原子处于扭曲的反式-C₃SnO₂三角双锥几何构型。苯环上两个庞大的叔丁基的存在阻止了涉及羟基取代基的任何氢键相互作用。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/63be/2969233/2357276384d6/e-65-0m808-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/63be/2969233/2357276384d6/e-65-0m808-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/63be/2969233/2357276384d6/e-65-0m808-fig1.jpg

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本文引用的文献

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A short history of SHELX.SHELX简史。
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