顺式 - [(7R,14R)-5,5,7,12,12,14 - 六甲基 - 1,4,8,11 - 四氮杂环十四烷 - κN](草酸根 - κO,O')镍(II) 草酸溶剂合物
cis-[(7R,14R)-5,5,7,12,12,14-Hexa-methyl-1,4,8,11-tetra-azacyclo-tetra-decane-κN](oxalato-κO,O')nickel(II) oxalic acid solvate.
作者信息
Ou Guang-Chuan, Dai Yong-Qiang, Tang Man-Sheng
机构信息
Department of Biology and Chemistry, Hunan University of Science and Engineering, Yongzhou Hunan 425100, People's Republic of China.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2009 Jun 6;65(Pt 7):m723. doi: 10.1107/S1600536809020042.
Abstract
Both mol-ecules of the title compound, [Ni(C(2)O(4))(C(16)H(36)N(4))]·C(2)H(2)O(4), are located on a crystallographic twofold rotation axis. The Ni(II) atom shows a distorted octa-hedral geometry. The crystal packing is stabilized by N-H⋯O and O-H⋯O hydrogen bonds.
摘要
标题化合物[Ni(C₂O₄)(C₁₆H₃₆N₄)]·C₂H₂O₄的两个分子均位于晶体学二重旋转轴上。Ni(II)原子呈现出扭曲的八面体几何构型。晶体堆积通过N—H⋯O和O—H⋯O氢键得以稳定。
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