Xu Chen, Cen Fei-Fei, Wang Zhi-Qiang, Zhang Yu-Qing
Acta Crystallogr Sect E Struct Rep Online. 2009 Jun 10;65(Pt 7):m754. doi: 10.1107/S160053680902145X.
In the planar [r.m.s. deviation 0.0265 Å] title compound, [Hg(C(7)H(5)O(2))Cl], the Hg(II) atom shows a typical linear coordination by a C atom of a benzene ring and a Cl atom. The benzene C atom and the aldehyde O atom chelate the Hg(II) atom by assuming the Hg⋯O separation of 2.817 (9) Å as a weak intra-molecular coordination bonding distance. The resulting five-membered metallacycle is nearly coplanar with the benzene ring dihedral angle 2.9 (1)°]. Inter-molecular O-H⋯O hydrogen bonds are present in the crystal structure, resulting in a one-dimensional supra-molecular architecture parallel to [201].
在平面[均方根偏差0.0265 Å]标题化合物[Hg(C₇H₅O₂)Cl]中,Hg(II)原子通过苯环的一个C原子和一个Cl原子呈现出典型的线性配位。苯环的C原子和醛基的O原子通过假定Hg⋯O间距为2.817 (9) Å作为弱分子内配位键距离来螯合Hg(II)原子。所得的五元金属环与苯环的二面角为2.9 (1)°,几乎共面。晶体结构中存在分子间O—H⋯O氢键,形成了平行于[201]的一维超分子结构。