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catena-Poly[hemi[bis-(4'-phenyl-2,2':6',2''-terpyridine-κN)copper(II)] [cuprate(I)-di-μ(2)-thio-cyanato-κN:S;κS:N]].链状聚[半[双-(4'-苯基-2,2':6',2''-三联吡啶-κN)铜(II)] [铜酸盐(I)-二-μ(2)-硫氰酸根合-κN:S;κS:N]]
Acta Crystallogr Sect E Struct Rep Online. 2009 Jun 20;65(Pt 7):m801. doi: 10.1107/S1600536809023009.

本文引用的文献

1
catena-Poly[hemi[bis-(4'-phenyl-2,2':6',2''-terpyridine-κN)copper(II)] [cuprate(I)-di-μ(2)-thio-cyanato-κN:S;κS:N]].链状聚[半[双-(4'-苯基-2,2':6',2''-三联吡啶-κN)铜(II)] [铜酸盐(I)-二-μ(2)-硫氰酸根合-κN:S;κS:N]]
Acta Crystallogr Sect E Struct Rep Online. 2009 Jun 20;65(Pt 7):m801. doi: 10.1107/S1600536809023009.
2
A short history of SHELX.SHELX简史。
Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22. doi: 10.1107/S0108767307043930. Epub 2007 Dec 21.
3
Recent developments in the supramolecular chemistry of terpyridine-metal complexes.三联吡啶-金属配合物超分子化学的最新进展。
Chem Soc Rev. 2004 Jul 30;33(6):373-99. doi: 10.1039/b400653b. Epub 2004 Jul 15.

链状聚[半{双-[4'-(3-吡啶基)-2,2':6',2''-三联吡啶-κN,N,N]铜(II)} [铜酸盐(I)-二-μ(2)-硫氰酸根合-κN:S;κS:N]]

catena-Poly[hemi{bis-[4'-(3-pyrid-yl)-2,2':6',2''-terpyridine-κN,N,N]copper(II)} [cuprate(I)-di-μ(2)-thio-cyanato-κN:S;κS:N]].

作者信息

Shi Wen-Juan

机构信息

Jiangxi Key Laboratory of Surface Engineering, Jiangxi Science and Technology Normal University, Jiangxi 330013, People's Republic of China.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2009 Jun 24;65(Pt 7):m814. doi: 10.1107/S1600536809023356.

DOI:10.1107/S1600536809023356
PMID:21582737
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2969290/
Abstract

The title compound, {[Cu(C(20)H(14)N(4))(2)][Cu(2)(NCS)(4)]}(n), was obtained by reacting copper acetate hydrate, ammonium thio-cyanate and 4'-(3-pyrid-yl)-2,2':6',2''-terpyridine (3-pytpy) under solvothermal conditions. The polymeric complex is isostructural with the 4'-phenyl-2,2':6',2''-terpyridine (phtpy) analogue. All intramolecular distances and angles are very similar for the two structures. Substitution of a phenyl group with a pyridyl group has no significant effect on the crystal packing which is accomplished by C-H⋯N and C-H⋯S hydrogen-bonding interactions.

摘要

标题化合物{[Cu(C₂₀H₁₄N₄)₂][Cu₂(NCS)₄]}ₙ是通过在溶剂热条件下使水合醋酸铜、硫氰酸铵与4'-(3-吡啶基)-2,2':6',2''-三联吡啶(3-pytpy)反应得到的。该聚合物配合物与4'-苯基-2,2':6',2''-三联吡啶(phtpy)类似物同构。两种结构的所有分子内距离和角度都非常相似。用吡啶基取代苯基对通过C-H⋯N和C-H⋯S氢键相互作用实现的晶体堆积没有显著影响。