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（丙酮-2κO）{μ-6,6'-二甲氧基-2,2'-[丙烷-1,2-二亚基双（腈基亚甲基）]二酚根合-κ1:2O，O，O，O:O，N，N'，O}三（硝酸根-1κO，O'）铜（II）钐（III）

(Acetone-2κO){μ-6,6'-dimeth-oxy-2,2'-[propane-1,2-diylbis(nitrilo-methyl-idyne)]diphenolato-κ1:2O,O,O,O:O,N,N',O}tris-(nitrato-1κO,O')copper(II)samarium(III).

作者信息

Sun Wen-Bin, Yan Peng-Fei, Li Hong-Feng, Gao Ting, Li Guang-Ming

机构信息

Key Laboratory of Functional Inorganic Material Chemistry (HLJU), Ministry of Education, School of Chemistry and Materials Science, Heilongjiang University, Harbin 150080, People's Republic of China.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2009 Jun 27;65(Pt 7):m840-1. doi: 10.1107/S160053680902399X.

DOI:10.1107/S160053680902399X
PMID:21582755
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2969449/
Abstract

In the title heteronuclear complex, [CuSm(C(19)H(20)N(2)O(4))(NO(3))(3)(CH(3)COCH(3))], the Cu(II) ion is five-coordinated by two O and two N atoms from the 6,6'-dimeth-oxy-2,2'-[propane-1,2-diylbis(nitrilo-methyl-idyne)]diphenolate ligand (L) and by an O atom from the acetone mol-ecule in a square-pyramidal geometry. The Sm(III) ion is ten-coordinated by six O atoms from the three nitrate ligands and four O atoms from the L ligand. In L, the C atoms of the diamino-propane fragment are disordered over two positions in a 0.674 (10):0.326 (10) ratio.

摘要

在标题异核配合物[CuSm(C₁₉H₂₀N₂O₄)(NO₃)₃(CH₃COCH₃)]中，Cu(II)离子由来自6,6'-二甲氧基-2,2'-[丙烷-1,2-二亚基双(腈基亚甲基)]二酚盐配体(L)的两个O原子和两个N原子以及来自丙酮分子的一个O原子以四方锥几何构型进行五配位。Sm(III)离子由来自三个硝酸根配体的六个O原子和来自L配体的四个O原子进行十配位。在L中，二氨基丙烷片段的C原子在两个位置上无序排列，比例为0.674 (10):0.326 (10)。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/febd/2969449/6dcbc9d7b761/e-65-0m840-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/febd/2969449/6dcbc9d7b761/e-65-0m840-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/febd/2969449/6dcbc9d7b761/e-65-0m840-fig1.jpg

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本文引用的文献

1
(Acetone-2κO){μ-6,6'-dimeth-oxy-2,2'-[propane-1,2-diylbis(nitrilo-methyl-idyne)]diphenolato-κ1:2O,O,O,O:O,N,N',O}tris(nitrato-1κO,O')copper(II)terbium(III).(丙酮-2κO){μ-6,6'-二甲氧基-2,2'-[丙烷-1,2-二亚基双(亚氨基甲基亚基)]二酚盐-κ1:2O,O,O,O:O,N,N',O}三(硝酸根-1κO,O')铜(II)铽(III)
Acta Crystallogr Sect E Struct Rep Online. 2009 Jun 17;65(Pt 7):m780-1. doi: 10.1107/S1600536809022077.
2
A short history of SHELX.SHELX简史。
Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22. doi: 10.1107/S0108767307043930. Epub 2007 Dec 21.