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二氯-2κCl-{μ-6,6'-二甲氧基-2,2'-[丙烷-1,3-二亚基双(腈基亚甲基)]二酚根合-1κO,N,N',O:2κO,O}铜(II)锌(II)

Dichlorido-2κCl-{μ-6,6'-dimeth-oxy-2,2'-[propane-1,3-diylbis(nitrilo-methyl-idyne)]diphenolato-1κO,N,N',O:2κO,O}copper(II)zinc(II).

作者信息

Liu Qingyun, Ge Shengsong, Cui Guangwen

机构信息

School of Chemical & Environmental Engineering, Shandong University of Science and Technology, Qingdao 266510, People's Republic of China.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2009 Mar 6;65(Pt 4):m359. doi: 10.1107/S1600536809006928.

DOI:10.1107/S1600536809006928
PMID:21582317
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2968792/
Abstract

In the title compound, [CuZnCl(2)(C(19)H(20)N(2)O(4))], the Cu(II) ion exhibits a slightly distorted square-planar coordination geometry defined by two N atoms and two O atoms of the 6,6'-dimeth-oxy-2,2'-[propane-1,3-diylbis(nitrilo-methyl-idyne)]diphenolate Schiff base ligand. The Zn(II) ion is also four-coordinated by the two phenolate O atoms of the Schiff base ligand and by two cis-coordinated chloride anions.

摘要

在标题化合物[CuZnCl₂(C₁₉H₂₀N₂O₄)]中，Cu(II)离子呈现出略微扭曲的平面正方形配位几何构型，由6,6'-二甲氧基-2,2'-[丙烷-1,3-二亚基双(亚氨甲基亚基)]二酚盐席夫碱配体的两个N原子和两个O原子定义。Zn(II)离子也通过席夫碱配体的两个酚盐O原子和两个顺式配位的氯离子进行四配位。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6768/2968792/5aaf22875e9a/e-65-0m359-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6768/2968792/5aaf22875e9a/e-65-0m359-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6768/2968792/5aaf22875e9a/e-65-0m359-fig1.jpg

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