{μ-6,6'-二甲氧基-2,2'-[丙烷-1,3-二亚基双(腈基亚甲基)]-二苯酚根}-三硝酸铜(II)镥(III)丙酮溶剂合物
{μ-6,6'-Dimeth-oxy-2,2'-[propane-1,3-diylbis(nitrilo-methyl-idyne)]-diphenolato}-trinitratocopper(II)lutetium(III) acetone solvate.
作者信息
Xing Jing-Chun, Xu Yong-Mei, Cui Xiao-Guang, Li Wen-Zhi
机构信息
Department of Anaesthesiology, The Second Affiliated Hospital, Harbin Medical University, Harbin 150081, People's Republic of China.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2009 Mar 25;65(Pt 4):m443. doi: 10.1107/S1600536809009581.
In the title complex, [CuLu(C(19)H(20)N(2)O(4))(NO(3))(3)]·CH(3)COCH(3), the Cu(II) ion is four-coordinated in a square-planar geometry by two O atoms and two N atoms from the deprotonated Schiff base. The Lu(III) ion is ten-coordinate, chelated by three nitrate groups and linked to the four O atoms of the deprotonated Schiff base. A mol-ecule of acetone is present as a solvate.
在标题配合物[CuLu(C₁₉H₂₀N₂O₄)(NO₃)₃]·CH₃COCH₃中，Cu(II)离子通过去质子化席夫碱的两个O原子和两个N原子以平面正方形几何构型进行四配位。Lu(III)离子为十配位，由三个硝酸根基团螯合，并与去质子化席夫碱的四个O原子相连。一个丙酮分子作为溶剂化物存在。
Zotero 插件