• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

{μ-6,6'-二甲氧基-2,2'-[丙烷-1,3-二亚基双(腈基亚甲基)]-二苯酚根}-三硝酸铜(II)镥(III)丙酮溶剂合物

{μ-6,6'-Dimeth-oxy-2,2'-[propane-1,3-diylbis(nitrilo-methyl-idyne)]-diphenolato}-trinitratocopper(II)lutetium(III) acetone solvate.

作者信息

Xing Jing-Chun, Xu Yong-Mei, Cui Xiao-Guang, Li Wen-Zhi

机构信息

Department of Anaesthesiology, The Second Affiliated Hospital, Harbin Medical University, Harbin 150081, People's Republic of China.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2009 Mar 25;65(Pt 4):m443. doi: 10.1107/S1600536809009581.

DOI:10.1107/S1600536809009581
PMID:21582380
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2968995/
Abstract

In the title complex, [CuLu(C(19)H(20)N(2)O(4))(NO(3))(3)]·CH(3)COCH(3), the Cu(II) ion is four-coordinated in a square-planar geometry by two O atoms and two N atoms from the deprotonated Schiff base. The Lu(III) ion is ten-coordinate, chelated by three nitrate groups and linked to the four O atoms of the deprotonated Schiff base. A mol-ecule of acetone is present as a solvate.

摘要

在标题配合物[CuLu(C₁₉H₂₀N₂O₄)(NO₃)₃]·CH₃COCH₃中，Cu(II)离子通过去质子化席夫碱的两个O原子和两个N原子以平面正方形几何构型进行四配位。Lu(III)离子为十配位，由三个硝酸根基团螯合，并与去质子化席夫碱的四个O原子相连。一个丙酮分子作为溶剂化物存在。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1e0a/2968995/f9226172598d/e-65-0m443-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1e0a/2968995/f9226172598d/e-65-0m443-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1e0a/2968995/f9226172598d/e-65-0m443-fig1.jpg

相似文献

1
{μ-6,6'-Dimeth-oxy-2,2'-[propane-1,3-diylbis(nitrilo-methyl-idyne)]-diphenolato}-trinitratocopper(II)lutetium(III) acetone solvate.{μ-6,6'-二甲氧基-2,2'-[丙烷-1,3-二亚基双(腈基亚甲基)]-二苯酚根}-三硝酸铜(II)镥(III)丙酮溶剂合物
Acta Crystallogr Sect E Struct Rep Online. 2009 Mar 25;65(Pt 4):m443. doi: 10.1107/S1600536809009581.
2
{μ-6,6'-Dimeth-oxy-2,2'-[propane-1,3-diylbis(nitrilo-methyl-idyne)]diphenolato}trinitratocopper(II)erbium(III) acetone solvate.{μ - 6,6'-二甲氧基 - 2,2'-[丙烷 - 1,3 - 二基双(腈基亚甲基)]二酚根合}三硝酸铜(II)铒(III)丙酮溶剂化物
Acta Crystallogr Sect E Struct Rep Online. 2009 Oct 3;65(Pt 11):m1299. doi: 10.1107/S1600536809037787.
3
{μ-6,6'-Dimeth-oxy-2,2'-[propane-1,3-diyl-bis(nitrilo-methyl-idyne)]-diphenolato}-trinitratocopper(II)samarium(III) acetone solvate.{μ - 6,6'-二甲氧基 - 2,2'-[丙烷 - 1,3 - 二基 - 双(腈基亚甲基)] - 二苯酚根合}-三硝酸铜(II)钐(III)丙酮溶剂合物
Acta Crystallogr Sect E Struct Rep Online. 2008 Jan 16;64(Pt 2):m344. doi: 10.1107/S1600536807061454.
4
{μ-6,6'-Dimeth-oxy-2,2'-[propane-1,3-diylbis(nitrilo-methyl-idyne)]diphenolato}trinitratocopper(II)europium(III).{μ-6,6'-二甲氧基-2,2'-[丙烷-1,3-二基双(亚氨基甲基亚基)]二酚根合}三硝酸铜(II)铕(III)
Acta Crystallogr Sect E Struct Rep Online. 2008 Aug 30;64(Pt 9):m1206. doi: 10.1107/S1600536808026329.
5
{μ-6,6'-Dimeth-oxy-2,2'-[cyclo-hexane-1,2-diylbis(nitrilo-methyl-idyne)]diphenolato}trinitratocopper(II)lutetium(III).{μ-6,6'-二甲氧基-2,2'-[环己烷-1,2-二亚基双(腈基亚甲基)]二酚根合}三硝酸铜(II)镥(III)
Acta Crystallogr Sect E Struct Rep Online. 2010 Nov 27;66(Pt 12):m1683-4. doi: 10.1107/S1600536810048245.
6
(Acetone-2κO){μ-6,6'-dimeth-oxy-2,2'-[propane-1,2-diylbis(nitrilo-methyl-idyne)]diphenolato-κ1:2O,O,O,O:O,N,N',O}tris-(nitrato-1κO,O')copper(II)samarium(III).（丙酮-2κO）{μ-6,6'-二甲氧基-2,2'-[丙烷-1,2-二亚基双（腈基亚甲基）]二酚根合-κ1:2O，O，O，O:O，N，N'，O}三（硝酸根-1κO，O'）铜（II）钐（III）
Acta Crystallogr Sect E Struct Rep Online. 2009 Jun 27;65(Pt 7):m840-1. doi: 10.1107/S160053680902399X.
7
(Acetone-2κO){μ-6,6'-dimeth-oxy-2,2'-[propane-1,2-diylbis(nitrilo-methyl-idyne)]diphenolato-κ1:2O,O,O,O:O,N,N',O}tris(nitrato-1κO,O')copper(II)terbium(III).(丙酮-2κO){μ-6,6'-二甲氧基-2,2'-[丙烷-1,2-二亚基双(亚氨基甲基亚基)]二酚盐-κ1:2O,O,O,O:O,N,N',O}三(硝酸根-1κO,O')铜(II)铽(III)
Acta Crystallogr Sect E Struct Rep Online. 2009 Jun 17;65(Pt 7):m780-1. doi: 10.1107/S1600536809022077.
8
{μ-6,6'-Dimeth-oxy-2,2'-[butane-1,4-diylbis(nitrilo-methanylyl-idene)]diphenolato}trinitratocopper(II)samarium(III).{μ-6,6'-二甲氧基-2,2'-[丁烷-1,4-二基双(亚氨甲基亚基)]二苯酚根}三硝酸铜(II)钐(III)
Acta Crystallogr Sect E Struct Rep Online. 2011 Sep 1;67(Pt 9):m1212. doi: 10.1107/S1600536811031138. Epub 2011 Aug 6.
9
{μ(2)-6,6'-Dimeth-oxy-2,2'-[butane-1,4-diylbis(nitrilo-methyl-idyne)]diphenolato}trinitratocopper(II)neodymium(III).{μ(2)-6,6'-二甲氧基-2,2'-[丁烷-1,4-二亚基双(次氮基甲基亚基)]二酚根合}三硝酸铜(II)钕(III)
Acta Crystallogr Sect E Struct Rep Online. 2010 Oct 20;66(Pt 11):m1423. doi: 10.1107/S1600536810040833.
10
{μ-6,6'-Dimeth-oxy-2,2'-[ethane-1,2-diylbis(nitrilo-methyl-idyne)]diphenolato-1κO,O,O,O:2κO,N,N',O}(methanol-1κO)(perchlorato-1κO)copper(II)sodium(I).{μ - 6,6'-二甲氧基 - 2,2'-[乙烷 - 1,2 - 二亚基双(腈基亚甲基)]二苯酚根合 - 1κO,O,O,O:2κO,N,N',O}(甲醇 - 1κO)(高氯酸根 - 1κO)铜(II)钠(I)
Acta Crystallogr Sect E Struct Rep Online. 2009 Mar 25;65(Pt 4):m445. doi: 10.1107/S1600536809010356.

引用本文的文献

1
{μ-6,6'-Dimeth-oxy-2,2'-[butane-1,4-diylbis(nitrilo-methanylyl-idene)]diphenolato}trinitratocopper(II)samarium(III).{μ-6,6'-二甲氧基-2,2'-[丁烷-1,4-二基双(亚氨甲基亚基)]二苯酚根}三硝酸铜(II)钐(III)
Acta Crystallogr Sect E Struct Rep Online. 2011 Sep 1;67(Pt 9):m1212. doi: 10.1107/S1600536811031138. Epub 2011 Aug 6.
2
{μ(2)-6,6'-Dimeth-oxy-2,2'-[butane-1,4-diylbis(nitrilo-methyl-idyne)]diphenolato}trinitratocopper(II)neodymium(III).{μ(2)-6,6'-二甲氧基-2,2'-[丁烷-1,4-二亚基双(次氮基甲基亚基)]二酚根合}三硝酸铜(II)钕(III)
Acta Crystallogr Sect E Struct Rep Online. 2010 Oct 20;66(Pt 11):m1423. doi: 10.1107/S1600536810040833.

本文引用的文献

1
A short history of SHELX.SHELX简史。
Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22. doi: 10.1107/S0108767307043930. Epub 2007 Dec 21.