8-溴-2-甲基喹啉
8-Bromo-2-methyl-quinoline.
作者信息
Yang Lin-Tao, Shen Fang, Ye Jiao, Wu Tian-Quan, Hu Ai-Xi
机构信息
College of Chemistry and Chemical Engineering, Hunan University, Changsha 410082, People's Republic of China.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2009 Jun 6;65(Pt 7):o1490. doi: 10.1107/S1600536809020625.
Abstract
In the crystal structure of the title compound, C(10)H(8)BrN, the dihedral angle between the two six-membered rings of the quinoline system is 0.49 (16)°. The mol-ecules are packed in a face-to-face arrangement fashion, with a centroid-centroid distance of 3.76 Å between the benzene and pyridine rings of adjacent mol-ecules. No hydrogen bonding is found in the crystal structure.
摘要
在标题化合物C(10)H(8)BrN的晶体结构中，喹啉体系的两个六元环之间的二面角为0.49 (16)°。分子以面对面排列的方式堆积，相邻分子的苯环和吡啶环之间的质心间距为3.76 Å。在晶体结构中未发现氢键。
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2
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