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ansa-桥连环戊二烯基钛配合物[{η-C(5)Me(4)CH(2)-C(NMe(2))=N}TiCl(2)]

The ansa-bridged cyclo-penta-dienyl titanium complex [{η-C(5)Me(4)CH(2)-C(NMe(2))=N}TiCl(2)].

作者信息

Guo Donglong, Tong Hong-Bo, Zhou Meisu

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2009 May 7;65(Pt 6):m611. doi: 10.1107/S1600536809015839.

DOI:10.1107/S1600536809015839
PMID:21582982
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2969701/
Abstract

The title complex, dichlorido[N,N-di-methyl-2-(η(5)-tetra-methyl-cyclo-penta-dien-yl)acetamidinido-κN']titanium(IV), [Ti(C(13)H(20)N(2))Cl(2)], exhibits an unusual ansa-bridged conformation. The cyclo-penta-dienyl ring and the mean plane of the Ti-N=C-C-C fragment form a dihedral angle of 88.08 (11)°.

摘要

标题配合物二氯代[N,N-二甲基-2-(η⁵-四甲基环戊二烯基)脒基-κN']钛(IV)，[Ti(C₁₃H₂₀N₂)Cl₂]，呈现出一种不寻常的桥连构象。环戊二烯基环与Ti-N=C-C-C片段的平均平面形成的二面角为88.08 (11)°。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3f9c/2969701/00bc89f7068f/e-65-0m611-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3f9c/2969701/00bc89f7068f/e-65-0m611-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3f9c/2969701/00bc89f7068f/e-65-0m611-fig1.jpg

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