ansa-桥连环戊二烯基钛配合物[{η-C(5)Me(4)CH(2)-C(NMe(2))=N}TiCl(2)]
The ansa-bridged cyclo-penta-dienyl titanium complex [{η-C(5)Me(4)CH(2)-C(NMe(2))=N}TiCl(2)].
作者信息
Guo Donglong, Tong Hong-Bo, Zhou Meisu
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2009 May 7;65(Pt 6):m611. doi: 10.1107/S1600536809015839.
Abstract
The title complex, dichlorido[N,N-di-methyl-2-(η(5)-tetra-methyl-cyclo-penta-dien-yl)acetamidinido-κN']titanium(IV), [Ti(C(13)H(20)N(2))Cl(2)], exhibits an unusual ansa-bridged conformation. The cyclo-penta-dienyl ring and the mean plane of the Ti-N=C-C-C fragment form a dihedral angle of 88.08 (11)°.
摘要
标题配合物二氯代[N,N-二甲基-2-(η⁵-四甲基环戊二烯基)脒基-κN']钛(IV)，[Ti(C₁₃H₂₀N₂)Cl₂]，呈现出一种不寻常的桥连构象。环戊二烯基环与Ti-N=C-C-C片段的平均平面形成的二面角为88.08 (11)°。
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