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[二（2,6 - 二氯亚苄基）丙烷 - 1,3 - 二胺 - κ(2)N,N']二溴化锌

[N,N'-Bis(2,6-dichloro-benzyl-idene)propane-1,3-diamine-κ(2)N,N']dibromidozinc.

作者信息

Khalaji Aliakbar Dehno, Grivani Gholamhossein, Seyyedi Mohammad, Fejfarová Karla, Dušek Michal

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2012 Jul 1;68(Pt 7):m971. doi: 10.1107/S1600536812027997. Epub 2012 Jun 23.

DOI:10.1107/S1600536812027997
PMID:22807790
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3393222/
Abstract

In the title compound, [ZnBr(2)(C(17)H(14)Cl(4)N(2))], the Zn(II) ion is bonded to two bromide ions and two N atoms of the diimine ligand and displays a moderately distorted tetra-hedral coordination geometry. The Schiff base ligand acts as a chelating ligand and coordinates to the Zn(II) atom via two N atoms.

摘要

在标题化合物[ZnBr₂(C₁₇H₁₄Cl₄N₂)]中，Zn(II)离子与两个溴离子和二亚胺配体的两个N原子键合，呈现出中度扭曲的四面体配位几何构型。席夫碱配体作为螯合配体，通过两个N原子与Zn(II)原子配位。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/202f/3393222/67fb24a9dba2/e-68-0m971-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/202f/3393222/67fb24a9dba2/e-68-0m971-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/202f/3393222/67fb24a9dba2/e-68-0m971-fig1.jpg

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本文引用的文献

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Synthesis, spectroscopic and thermal studies of some IIB group complexes with a new N2-Schiff base ligand.IIB 族配合物与新型 N2-席夫碱配体的合成、光谱和热研究。
Spectrochim Acta A Mol Biomol Spectrosc. 2011 Oct 15;81(1):122-7. doi: 10.1016/j.saa.2011.05.066. Epub 2011 Jun 17.
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Dibromido{2-[(4-bromo-phen-yl)imino-meth-yl]pyridine-κN,N'}zinc(II).
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