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{N,N'-双[1-(2-吡啶基)亚乙基]丙烷-1,2-二胺-κN,N',N'',N'''}双(硫氰酸根合-κN)锰(II)

{N,N'-Bis[1-(2-pyrid-yl)ethyl-idene]propane-1,2-diamine-κN,N',N'',N'''}bis-(thio-cyanato-κN)manganese(II).

作者信息

Wang Fu-Ming

机构信息

Department of Chemistry, Dezhou University, Dezhou Shandong 253023, People's Republic of China.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2010 Jun 16;66(Pt 7):m777. doi: 10.1107/S1600536810021549.

DOI:10.1107/S1600536810021549
PMID:21587705
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3006985/
Abstract

In the title compound, [Mn(NCS)(2)(C(17)H(20)N(4))], the Mn(II) atom is six-coordinated by the N,N',N'',N'''-tetra-dentate Schiff base ligand and by two trans-N atoms from two thio-cyanate anions, forming a distorted octa-hedral geometry. The dihedral angle between the aromatic rings of the Schiff base is 9.5 (3)°.

摘要

在标题化合物[Mn(NCS)₂(C₁₇H₂₀N₄)]中，Mn(II)原子由N,N',N'',N'''-四齿席夫碱配体以及来自两个硫氰酸根阴离子的两个反式N原子进行六配位，形成扭曲的八面体几何构型。席夫碱的芳环之间的二面角为9.5 (3)°。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/eec4/3006985/ae492e0908e0/e-66-0m777-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/eec4/3006985/ae492e0908e0/e-66-0m777-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/eec4/3006985/ae492e0908e0/e-66-0m777-fig1.jpg

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