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双[2-(2H-苯并三唑-2-基)-4-甲基苯酚根]钯(II)

Bis[2-(2H-benzotriazol-2-yl)-4-methylphenolato]palladium(II).

作者信息

Tsai Chen-Yen, Lin Chia-Her, Ko Bao-Tsan

机构信息

Department of Chemistry, Chung-Yuan Christian University, Chung-Li 320, Taiwan.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2009 May 7;65(Pt 6):m619. doi: 10.1107/S1600536809016390.

DOI:10.1107/S1600536809016390
PMID:21582989
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2969542/
Abstract

In the title complex, [Pd(C(13)H(10)N(3)O)(2)], the Pd(II) atom is tetra-coordinated by two N atoms and two O atoms from two bidentate 2-(2H-benzotriazol-2-yl)-4-methylphenolate ligands, forming a square-planar environment. The asymmetric unit contains one half mol-ecule in which the Pd atom lies on a centre of symmetry.

摘要

在标题配合物[Pd(C₁₃H₁₀N₃O)₂]中，Pd(II)原子由来自两个双齿2-(2H-苯并三唑-2-基)-4-甲基苯酚盐配体的两个N原子和两个O原子进行四配位，形成一个平面正方形环境。不对称单元包含半个分子，其中Pd原子位于对称中心上。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2901/2969542/bc6c4d4bd705/e-65-0m619-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2901/2969542/b2435e7340f9/e-65-0m619-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2901/2969542/bc6c4d4bd705/e-65-0m619-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2901/2969542/b2435e7340f9/e-65-0m619-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2901/2969542/bc6c4d4bd705/e-65-0m619-fig2.jpg

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