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双{1-[(E)-(2-甲基苯基)重氮基]-2-萘酚根合}钯(II)

Bis{1-[(E)-(2-methyl-phen-yl)diazen-yl]-2-naphtho-lato}palladium(II).

作者信息

Lin Meng-Ling, Tsai Chen-Yen, Li Chen-Yu, Huang Bor-Hunn, Ko Bao-Tsan

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2010 Jul 24;66(Pt 8):m1022. doi: 10.1107/S1600536810028916.

DOI:10.1107/S1600536810028916
PMID:21588097
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3007315/
Abstract

In the title compound, [Pd(C(17)H(13)N(2)O)(2)], the Pd(II) atom is tetra-coordinated by two N atoms and two O atoms from two bidentate methylphenyl-diazenylnaphtolate ligands, forming a square-planar complex. The two N atoms and two O atoms around the Pd(II) atom are trans to each other (as the Pd(II) atom lies on a crystallographic inversion centre) with O-Pd-N bond angles of 89.60 (11) and 90.40 (11)°. The distances between the Pd(II) atom and the coordinated O and N atoms are 1.966 (3) and 2.009 (3) Å, respectively.

摘要

在标题化合物[Pd(C₁₇H₁₃N₂O)₂]中，Pd(II)原子由来自两个双齿甲基苯基重氮萘酚配体的两个N原子和两个O原子四配位，形成一个平面正方形配合物。Pd(II)原子周围的两个N原子和两个O原子彼此反式排列（因为Pd(II)原子位于一个晶体学反演中心上），O-Pd-N键角为89.60(11)°和90.40(11)°。Pd(II)原子与配位的O和N原子之间的距离分别为1.966(3) Å和2.009(3) Å。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2a36/3007315/d6eca11d51d2/e-66-m1022-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2a36/3007315/d6eca11d51d2/e-66-m1022-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2a36/3007315/d6eca11d51d2/e-66-m1022-fig1.jpg

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