2-(3-Pyridinio)benzimidazolium penta-chloridoanti-monate(III) monohydrate.
作者信息
Cui Li-Jing, Xu Hai-Jun, Pan Ke-Ji
机构信息
Ordered Matter Science Research Center, College of Chemistry and Chemical Engineering, Southeast University, Nanjing 211189, People's Republic of China.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2009 May 23;65(Pt 6):m674. doi: 10.1107/S1600536809018935.
Abstract
In the title compound, (C(12)H(11)N(3))[SbCl(5)]·H(2)O, the Sb(III) centre is surrounded by five Cl atoms and displays a distorted square-pyramidal coordination geometry. The dihedral angle formed by the plane of the imidazole ring system with the pyridine ring is 4.380 (15)°. The crystal structure is stabilized by N-H⋯Cl, O-H⋯Cl and N-H⋯O hydrogen bonds, forming a three-dimensional network.
摘要
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