Chen Li Zhuang
Ordered Matter Science Research Center, College of Chemistry and Chemical Engineering, Southeast University, Nanjing 210096, People's Republic of China.
Acta Crystallogr Sect E Struct Rep Online. 2009 May 29;65(Pt 6):m689. doi: 10.1107/S1600536809019345.
The asymmetric unit of the title compound, (C(4)H(10)NO)(2)[SbCl(5)], consists of two morpholinium cations in chair conformations, and a penta-chloridoanti-monate dianion with the Sb(III) ion in a slightly distorted square-pyramidal coordination environment. The morpholinium cations are connected to each other by N-H⋯O hydrogen bonds, and they link the chloride anions and the anti-monate SbCl(3) group via N-H⋯Cl contacts.
标题化合物(C₄H₁₀NO)₂[SbCl₅]的不对称单元由两个呈椅式构象的吗啉鎓阳离子以及一个五氯合锑酸二价阴离子组成,其中Sb(III)离子处于略微扭曲的四方锥配位环境中。吗啉鎓阳离子通过N-H⋯O氢键相互连接,并通过N-H⋯Cl接触将氯离子和锑酸根SbCl₃基团连接起来。