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Dibromido(2,2':6',2''-terpyridine-κN,N',N'')zinc(II).

作者信息

Zhao Qing-Lan, Li Guo-Peng

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2009 May 29;65(Pt 6):m693. doi: 10.1107/S1600536809019266.

DOI:10.1107/S1600536809019266
PMID:21583049
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2969570/
Abstract

In the title compound, [ZnBr(2)(C(15)H(11)N(3))], the Zn(II) ion is five-coordinated by the three N atoms from a 2,2':6',2''-terpyridine ligand (terpy) and two bromide anions in a distorted trigonal bipyramidal configuration. Each mol-ecule is situated on a twofold rotational axis that passes through the Zn(II) ion and the central ring of the terpy ligand. In the crystal structure, aromatic π-π inter-actions between terpy ligands [centroid-centroid distances = 3.6265 (9) Å] link mol-ecules into stacks propagated in the [001] direction.

摘要
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2972/2969570/9c781d72a898/e-65-0m693-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2972/2969570/623d0305dd43/e-65-0m693-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2972/2969570/9c781d72a898/e-65-0m693-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2972/2969570/623d0305dd43/e-65-0m693-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2972/2969570/9c781d72a898/e-65-0m693-fig2.jpg

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引用本文的文献

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Acta Crystallogr Sect E Struct Rep Online. 2009 Apr 2;65(Pt 5):m483-4. doi: 10.1107/S1600536809009994.
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A short history of SHELX.SHELX简史。
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