二溴（2,9-二甲基-1,10-菲咯啉-κN,N'）汞（II）
Dibromido(2,9-dimethyl-1,10-phenanthroline-κN,N')mercury(II).
作者信息
Alizadeh Robabeh, Heidari Amene, Ahmadi Roya, Amani Vahid
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2009 Apr 2;65(Pt 5):m483-4. doi: 10.1107/S1600536809009994.
In the mol-ecule of the title compound, [HgBr(2)(C(14)H(12)N(2))], the Hg(II) atom is four-coordinated in a distorted tetra-hedral configuration by two N atoms from a 2,9-dimethyl-1,10-phenanthroline ligand and by two Br atoms. In the crystal structure, weak inter-molecular C-H⋯Br hydrogen bonds link the mol-ecules into chains along the b axis. There are π-π contacts between the phenanthroline rings [centroid-centroid distances = 3.806 (4), 3.819 (4), 3.739 (3), 3.690 (3), 3.619 (4) and 3.674 (3) Å].
在标题化合物[HgBr₂(C₁₄H₁₂N₂)]的分子中，Hg(II)原子通过来自2,9-二甲基-1,10-菲咯啉配体的两个N原子和两个Br原子以扭曲的四面体构型进行四配位。在晶体结构中，弱的分子间C—H⋯Br氢键将分子沿b轴连接成链。菲咯啉环之间存在π-π接触[质心-质心距离 = 3.806 (4)、3.819 (4)、3.739 (3)、3.690 (3)、3.619 (4)和3.674 (3) Å]。
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