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二氯{2-[(4-碘苯基)亚氨基甲基]吡啶-κN,N'}铜(II)

Dichlorido{2-[(4-iodo-phen-yl)imino-meth-yl]pyridine-κN,N'}copper(II).

作者信息

Mahmoudi Ali, Khalaj Mehdi, Gao Shan, Ng Seik Weng, Mohammadgholiha Mahmoud

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2009 Apr 22;65(Pt 5):m555. doi: 10.1107/S1600536809011684.

DOI:10.1107/S1600536809011684
PMID:21583788
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2977602/
Abstract

The Cu(II) atom in the title complex, [CuCl(2)(C(12)H(9)IN(2))], has a square-planar coordination being N,N'-chelated by the Schiff base ligand, and by two Cl atoms. The geometry is distorted towards square pyramidal owing to a long Cu⋯Cl inter-action of 2.941 (1) Å. This results in the formation of a zigzag chain structure propagating in the c-axis direction.

摘要

在标题配合物[CuCl₂(C₁₂H₉IN₂)]中，铜(II)原子具有平面正方形配位，被席夫碱配体以及两个氯原子进行N,N'-螯合。由于Cu⋯Cl间存在2.941 (1) Å的长相互作用，其几何形状向四方锥畸变。这导致形成了沿c轴方向延伸的锯齿链结构。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d3e8/2977602/1fdb1e1be96f/e-65-0m555-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d3e8/2977602/4a20b6523d23/e-65-0m555-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d3e8/2977602/1fdb1e1be96f/e-65-0m555-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d3e8/2977602/4a20b6523d23/e-65-0m555-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d3e8/2977602/1fdb1e1be96f/e-65-0m555-fig2.jpg

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引用本文的文献

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