2,10 - 二羟基 - 13 - 甲基 - 13 - 氮杂四环 - [9.3.1.0.0]十五碳 - 3(8),4,6 - 三烯 - 9,15 - 二酮
2,10-Dihydr-oxy-13-methyl-13-aza-tetra-cyclo-[9.3.1.0.0]penta-deca-3(8),4,6-triene-9,15-dione.
作者信息
Suresh J, Nithya U C, Kumar R Suresh, Perumal S, Lakshman P L Nilantha
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2009 May 7;65(Pt 6):o1216. doi: 10.1107/S1600536809015785.
Abstract
In the title compound, C(15)H(15)NO(4), the n-methyl-piperidone ring adopts a chair conformation and both five-membered rings adopt a twist conformation. An intra-molecular O-H⋯O hydrogen bond is observed. Inversion-related mol-ecules are linked into R(2) (2)(10) dimers by pairs of O-H⋯O hydrogen bonds. The crystal structure is further stabilized by C-H⋯O hydrogen bonds.
摘要
在标题化合物C(15)H(15)NO(4)中，N-甲基哌啶酮环呈椅式构象，两个五元环均呈扭曲构象。观察到分子内O-H⋯O氢键。通过O-H⋯O氢键对，与反演相关的分子连接成R(2) (2)(10)二聚体。晶体结构通过C-H⋯O氢键进一步稳定。
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