1,4-重氮双环-[2.2.2]辛烷二水二氯（草酸根-κO,O'）铁（III）氯化物
1,4-Diazo-niabicyclo-[2.2.2]octane diaqua-dichlorido-(oxalato-κO,O')iron(III) chloride.
作者信息
Cai Ying
机构信息
Ordered Matter Science Research Center, Southeast University, Nanjing 211189, People's Republic of China.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2009 Jul 8;65(Pt 8):m877. doi: 10.1107/S1600536809025628.
In the title compound, (C(6)H(14)N(2))[Fe(C(2)O(4))Cl(2)(H(2)O)(2)]Cl, all ions are situated on twofold rotational axes. The Fe(III) ion is coordinated by two O atoms from a chelating oxalate ligand, two water mol-ecules and two chloride anions in a distorted octa-hedral geometry. Inter-molecular N-H⋯O, O-H⋯O and O-H⋯Cl hydrogen bonds form an extensive three-dimensional network which consolidates the crystal packing.
在标题化合物（C₆H₁₄N₂）[Fe（C₂O₄）Cl₂（H₂O）₂]Cl中，所有离子都位于二重旋转轴上。Fe（III）离子由来自一个螯合草酸根配体的两个O原子、两个水分子和两个氯离子以扭曲的八面体几何构型配位。分子间的N-H⋯O、O-H⋯O和O-H⋯Cl氢键形成了一个广泛的三维网络，巩固了晶体堆积。
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