苄基·氯代双（喹啉 - 8 - 醇根）锡（IV）
Benzyl-chloridobis(quinolin-8-olato)tin(IV).
作者信息
Wang Qibao
机构信息
Department of Pharmacy, Jining Medical College, No. 669 Xueyuan Road, Rizhao, Shandong 276826, People's Republic of China.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2009 Jul 11;65(Pt 8):m905. doi: 10.1107/S1600536809025902.
In the title compound, [Sn(C(7)H(7))(C(9)H(6)NO)(2)Cl], the Sn(IV) ion is in a distorted octa-hedral coordination environment formed by the O and N atoms of two bis-chelating quinolin-8-olate ligands, a Cl atom and a C atom from a benzyl ligand. The axial sites are occupied by an N atom of a quinolinate ligand and the C atom of the benzyl ligand. The axial Sn-N bond is slightly shorter than the equatorial Sn-N bond.
在标题化合物[Sn(C₇H₇)(C₉H₆NO)₂Cl]中，Sn(IV)离子处于由两个双螯合喹啉 - 8 - 醇盐配体的O和N原子、一个Cl原子以及一个来自苄基配体的C原子形成的扭曲八面体配位环境中。轴向位置由喹啉酸酯配体的一个N原子和苄基配体的C原子占据。轴向的Sn - N键比赤道面的Sn - N键略短。
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