二氯双（2-氯苄基）（喹啉-8-醇根合-κN，O）锡（IV）
Chloridobis(2-chloro-benz-yl)(quinolin-8-olato-κN,O)tin(IV).
作者信息
Keng Thy Chun, Lo Kong Mun, Ng Seik Weng
机构信息
Department of Chemistry, University of Malaya, 50603 Kuala Lumpur, Malaysia.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2011 Jun 1;67(Pt 6):m663. doi: 10.1107/S160053681101573X. Epub 2011 May 7.
Abstract
The Sn(IV) atom in the three independent mol-ecules of the title compound, [Sn(C(7)H(6)Cl)(2)(C(9)H(6)NO)Cl], is N,O-chelated by the quinolin-8-olate anion and exists in a cis-C(2)SnNOCl trigonal-bipyramidal geometry; the O atom of the anion and the two benzyl C atoms lie in the equatorial plane.
摘要
在标题化合物[Sn(C₇H₆Cl)₂(C₉H₆NO)Cl]的三个独立分子中，Sn(IV)原子被喹啉-8-olate阴离子进行N,O-螯合，以顺式-C₂SnNOCl三角双锥几何构型存在；阴离子的O原子和两个苄基C原子位于赤道平面。
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