双（1,10-菲咯啉-κN,N'）（硫酸根-κO,O'）镍（II）乙二醇溶剂化物。
Bis(1,10-phenanthroline-κN,N')(sulfato-κO,O')nickel(II) ethane-1,2-diol solvate.
作者信息
Zhong Kai-Long, Ni Chao, Wang Jian-Mei
机构信息
Department of Applied Chemistry, Nanjing College of Chemical Technology, Nanjing, Jiangsu Province, People's Republic of China.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2009 Jul 11;65(Pt 8):m911. doi: 10.1107/S1600536809026269.
Abstract
In the title compound, [Ni(SO(4))(C(12)H(8)N(2))(2)]·C(2)H(6)O(2), the coordination polyhedron around the Ni(2+) ion is a distorted octahedron, with four N atoms from two phenanthroline groups and two O atoms from a bidentate sulfate ligand. The Ni(2+) ion lies on a special position of site symmetry 2. Inter-molecular O-H⋯O hydrogen bonds help to stabilize the structure. The OH group of the ethane-1,2-diol solvent is disordered over two positions with equal occupancy.
摘要
在标题化合物[Ni(SO₄)(C₁₂H₈N₂)₂]·C₂H₆O₂中，Ni²⁺离子周围的配位多面体是一个扭曲的八面体，有来自两个菲咯啉基团的四个N原子和来自一个双齿硫酸根配体的两个O原子。Ni²⁺离子位于对称点群为2的特殊位置上。分子间的O—H⋯O氢键有助于稳定该结构。乙烷-1,2-二醇溶剂的OH基团在两个位置上无序分布，占有率相等。
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