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双{1-[(4-甲基-苯基)亚氨基甲基]-2-萘酚根合-κN,O}镍(II)

Bis{1-[(4-methyl-phen-yl)imino-meth-yl]-2-naphtho-lato-κN,O}nickel(II).

作者信息

Wang Quanbo, Jiang Jianzhuang, Zhu Peihua

机构信息

School of Chemistry & Chemical Engineering, Shandong University, Jinan 250100, People's Republic of China.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2011 Apr 1;67(Pt 4):m470. doi: 10.1107/S1600536811010087. Epub 2011 Mar 23.

DOI:10.1107/S1600536811010087
PMID:21753985
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3099807/
Abstract

In the title complex, [Ni(C(18)H(14)NO)(2)], the Ni(II) ion lies on an inversion center and is coordinated in a slightly distorted square-planar environment. The 1-[(4-methyl-phen-yl)imino-meth-yl]-2-naphtho-late ligands are coordinated in a trans arrangement with respect to the N and O atoms. In the symmetry-unique ligand, the dihedral angle between the naphthalene ring system and the benzene ring of the methyl-phenyl group is 49.03 (7)°.

摘要

在标题配合物[Ni(C₁₈H₁₄NO)₂]中，Ni(II)离子位于一个对称中心上，并在一个轻微扭曲的平面正方形环境中配位。1-[(4-甲基苯基)亚氨基甲基]-2-萘酚配体相对于N和O原子呈反式排列。在对称独立的配体中，萘环系统与甲基苯基的苯环之间的二面角为49.03 (7)°。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b873/3099807/9f12bd88650f/e-67-0m470-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b873/3099807/9f12bd88650f/e-67-0m470-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b873/3099807/9f12bd88650f/e-67-0m470-fig1.jpg

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