氯（1,3 - 二甲基硫脲 - κS）双（三苯基膦 - κP）铜（I）乙腈半溶剂合物
Chlorido(1,3-dimethyl-thio-urea-κS)bis-(triphenyl-phosphine-κP)copper(I) acetonitrile hemisolvate.
作者信息
La-O Latipah, Pakawatchai Chaveng, Saithong Saowanit, Skelton Brian W
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2009 Jul 15;65(Pt 8):m926. doi: 10.1107/S1600536809026798.
The title compound, [CuCl(C(3)H(8)N(2)S)(C(18)H(15)P)(2)]·0.5CH(3)CN, was prepared by the reaction of copper(I) chloride with 1,3-dimethyl-thio-urea (dmtu) and triphenyl-phosphine (PPh(3)) in acetonitrile. The Cu(I) atom has a distorted tetra-hedral environment formed by two P atoms from triphenyl-phosphine, one S atom from the dmtu ligand and one Cl atom. In addition, the mol-ecules exhibit intra- and inter-molecular N-H⋯Cl inter-actions.
标题化合物[CuCl(C₃H₈N₂S)(C₁₈H₁₅P)₂]·0.5CH₃CN是通过氯化亚铜与1,3-二甲基硫脲（dmtu）和三苯基膦（PPh₃）在乙腈中反应制备的。Cu(I)原子具有由来自三苯基膦的两个P原子、来自dmtu配体的一个S原子和一个Cl原子形成的扭曲四面体环境。此外，分子表现出分子内和分子间的N-H⋯Cl相互作用。
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