[1,1'-双（二环己基膦基）钴鎓-κP，P']氯（η-环戊二烯基）钌（II）六氟磷酸盐
[1,1'-Bis(dicyclo-hexyl-phosphino)cobalto-cenium-κP,P']chlorido(η-cyclo-penta-dien-yl)ruthenium(II) hexa-fluorido-phosphate.
作者信息
Hou Jian-Guo
机构信息
Department of Biotic Environment, Nanchang Instiute of Technology, Nanchang 330013, People's Republic of China.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2010 Jan 30;66(Pt 2):m218. doi: 10.1107/S1600536810001790.
In the title structure, [CoRu(C(5)H(5))(C(17)H(26)P)(2)Cl]PF(6), the Ru(II) atom is bonded to a cyclo-penta-dienyl ring, a Cl atom and two P atoms of the chelating 1,1'-bis-(dicyclo-hexyl-phosphino)cobaltocenium (di-cypc) ligand, leading to a three-legged piano-stool coordination. Part of the PF(6) (-) counter-anion is disordered over two positions, with a site-occupancy ratio of 0.898 (7):0.102 (7). The components are linked by C-H⋯F and C-H⋯Cl hydrogen bonds.
在标题结构[CoRu(C₅H₅)(C₁₇H₂₆P)₂Cl]PF₆中，Ru(II)原子与一个环戊二烯基环、一个Cl原子以及螯合的1,1'-双（二环己基膦基）钴茂（二-环戊基环戊二烯基钴）配体的两个P原子键合，形成一个三腿钢琴凳式配位。部分PF₆⁻抗衡阴离子在两个位置上无序排列，占位比为0.898 (7):0.102 (7)。各组分通过C-H⋯F和C-H⋯Cl氢键相连。
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