• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

[1,1'-双（二环己基膦基）钴鎓-κP，P']氯（η-环戊二烯基）钌（II）六氟磷酸盐

[1,1'-Bis(dicyclo-hexyl-phosphino)cobalto-cenium-κP,P']chlorido(η-cyclo-penta-dien-yl)ruthenium(II) hexa-fluorido-phosphate.

作者信息

Hou Jian-Guo

机构信息

Department of Biotic Environment, Nanchang Instiute of Technology, Nanchang 330013, People's Republic of China.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2010 Jan 30;66(Pt 2):m218. doi: 10.1107/S1600536810001790.

DOI:10.1107/S1600536810001790
PMID:21579679
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2979948/
Abstract

In the title structure, [CoRu(C(5)H(5))(C(17)H(26)P)(2)Cl]PF(6), the Ru(II) atom is bonded to a cyclo-penta-dienyl ring, a Cl atom and two P atoms of the chelating 1,1'-bis-(dicyclo-hexyl-phosphino)cobaltocenium (di-cypc) ligand, leading to a three-legged piano-stool coordination. Part of the PF(6) (-) counter-anion is disordered over two positions, with a site-occupancy ratio of 0.898 (7):0.102 (7). The components are linked by C-H⋯F and C-H⋯Cl hydrogen bonds.

摘要

在标题结构[CoRu(C₅H₅)(C₁₇H₂₆P)₂Cl]PF₆中，Ru(II)原子与一个环戊二烯基环、一个Cl原子以及螯合的1,1'-双（二环己基膦基）钴茂（二-环戊基环戊二烯基钴）配体的两个P原子键合，形成一个三腿钢琴凳式配位。部分PF₆⁻抗衡阴离子在两个位置上无序排列，占位比为0.898 (7):0.102 (7)。各组分通过C-H⋯F和C-H⋯Cl氢键相连。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/374f/2979948/71d4435f407d/e-66-0m218-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/374f/2979948/d4f7fc4ad9da/e-66-0m218-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/374f/2979948/71d4435f407d/e-66-0m218-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/374f/2979948/d4f7fc4ad9da/e-66-0m218-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/374f/2979948/71d4435f407d/e-66-0m218-fig2.jpg

相似文献

1
[1,1'-Bis(dicyclo-hexyl-phosphino)cobalto-cenium-κP,P']chlorido(η-cyclo-penta-dien-yl)ruthenium(II) hexa-fluorido-phosphate.[1,1'-双（二环己基膦基）钴鎓-κP，P']氯（η-环戊二烯基）钌（II）六氟磷酸盐
Acta Crystallogr Sect E Struct Rep Online. 2010 Jan 30;66(Pt 2):m218. doi: 10.1107/S1600536810001790.
2
[1,1'-Bis(di-phenyl-phosphan-yl)cobalto-cenium-κ(2) P,P'](η(5)-cyclo-penta-dien-yl){2-[4-(4-ethynylphen-yl)phen-yl]ethynyl-κC}ruthenium(II) hexa-fluorido-phosphate.[1,1'-双（二苯基膦基）钴鎓-κ(2) P,P'](η(5)-环戊二烯基){2-[4-(4-乙炔基苯基)苯基]乙炔基-κC}钌(II) 六氟磷酸酯
Acta Crystallogr Sect E Struct Rep Online. 2013 Oct 19;69(Pt 11):m607. doi: 10.1107/S1600536813028195.
3
[1,1'-Bis(diphenyl-phosphino)cobalto-cenium-κP,P']dichloridoplatinum(II) hexa-fluorido-phosphate.[1,1'-双（二苯基膦基）钴鎓-κP,P']二氯铂（II）六氟磷酸盐
Acta Crystallogr Sect E Struct Rep Online. 2009 Jul 22;65(Pt 8):m960. doi: 10.1107/S1600536809027925.
4
[1,1'-Bis(diphenyl-phosphan-yl)cobalto-cenium]carbonyl-chloridohydrido(triphenyl-phosphane)ruthenium(II) hexa-fluoridophosphate dichloro-methane disolvate.[1,1'-双（二苯基膦基）钴鎓]羰基氯氢（三苯基膦）钌（II）六氟磷酸盐二氯甲烷溶剂化物
Acta Crystallogr Sect E Struct Rep Online. 2011 Dec 1;67(Pt 12):m1671-2. doi: 10.1107/S1600536811044035. Epub 2011 Nov 5.
5
1,1'-Bis(diisobutyl-phosphino)cobalto-cenium hexa-fluorido-phosphate.1,1'-双（二异丁基膦基）钴鎓六氟磷酸酯
Acta Crystallogr Sect E Struct Rep Online. 2008 Jun 19;64(Pt 7):m927. doi: 10.1107/S1600536808017194.
6
(η-Penta-methyl-cyclo-penta-dien-yl)(η-toluene)-ruthenium(II) hexa-fluorido-phosphate.（η-五甲基环戊二烯基）（η-甲苯）钌（II）六氟磷酸盐
Acta Crystallogr Sect E Struct Rep Online. 2010 Sep 15;66(Pt 10):m1264. doi: 10.1107/S1600536810036299.
7
[1,2-Bis(diphenyl-phosphino)ethane]-chlorido(η-penta-methyl-cyclo-penta-dien-yl)iron(II) dichloro-methane solvate.
Acta Crystallogr Sect E Struct Rep Online. 2010 Jul 10;66(Pt 8):m921. doi: 10.1107/S1600536810026784.
8
Chlorido[1-(diphenyl-phosphan-yl)cobaltocenium]gold(I) hexa-fluoridophosphate.六氟磷酸氯代[1-(二苯基膦基)钴茂鎓]金(I)
Acta Crystallogr Sect E Struct Rep Online. 2011 Jun 1;67(Pt 6):m798. doi: 10.1107/S1600536811018769. Epub 2011 May 25.
9
(R,R(Fc),S(Ru))-Chlorido(η-p-cymene){1-[1-(diphenyl-phosphanyl)ethyl]-2-[2-(diphenyl-phosphanyl)phenyl]ferrocene-κP,P'}ruthenium(II) hexa-fluorido-phosphate.（R，R（Fc），S（Ru））-氯（η-对异丙基苯）{1-[1-（二苯基膦基）乙基]-2-[2-（二苯基膦基）苯基]二茂铁-κP，P′}钌（II）六氟磷酸酯
Acta Crystallogr Sect E Struct Rep Online. 2011 Oct 1;67(Pt 10):m1379-80. doi: 10.1107/S1600536811036506. Epub 2011 Sep 14.
10
Tri-μ-chlorido-bis-[(η(5)-penta-methyl-cyclo-penta-dien-yl)rhodium(III)] hexa-fluorido-phosphate from synchrotron radiation.来自同步辐射的三-μ-氯代-双-[(η(5)-五甲基-环戊二烯基)铑(III)]六氟磷酸酯
Acta Crystallogr Sect E Struct Rep Online. 2013 Dec 11;70(Pt 1):m14-5. doi: 10.1107/S1600536813032480. eCollection 2014 Jan 1.

本文引用的文献

1
A short history of SHELX.SHELX简史。
Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22. doi: 10.1107/S0108767307043930. Epub 2007 Dec 21.