（η-环戊二烯基）（丙腈-κN）双（三苯基膦-κP）钌（II）三氟甲磺酸盐
(η-Cyclo-penta-dien-yl)(propionitrile-κN)bis-(triphenyl-phosphine-κP)ruthenium(II) trifluoro-methane-sulfonate.
作者信息
Mauthner Klaus, Kirchner Karl, Mereiter Kurt
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2009 Oct 3;65(Pt 11):m1267. doi: 10.1107/S1600536809038720.
The title compound, [Ru(C(5)H(5))(C(3)H(5)N)(C(18)H(15)P)(2)]CF(3)SO(3), forms yellow crystals with a distinctly hemimorphic habit. It contains a half-sandwich complex of ruthenium with a three-legged piano-stool geometry, with Ru-P = 2.3585 (4) and 2.3312 (4) Å, and Ru-N = 2.0422 (15) Å as the legs. The CF(3)SO(3) (-) anion is anchored in the crystal lattice by C-H⋯O and C-H⋯F hydrogen bonds, with C⋯F,O distances starting at 3.125 (2) Å.
标题化合物[Ru(C₅H₅)(C₃H₅N)(C₁₈H₁₅P)₂]CF₃SO₃形成具有明显异极习性的黄色晶体。它包含一个钌的半夹心配合物，具有三脚钢琴凳几何结构，Ru-P键长为2.3585 (4) 和2.3312 (4) Å，Ru-N键长为2.0422 (15) Å作为凳腿。CF₃SO₃⁻阴离子通过C-H⋯O和C-H⋯F氢键锚定在晶格中，C⋯F、O距离起始于3.125 (2) Å。
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