双[μ(2)-1,2-双-(咪唑-1-基甲基)苯-κN:N]双[二氯锌(II)]
Bis[μ(2)-1,2-bis-(imidazol-1-ylmeth-yl)benzene-κN:N]bis-[dichloridozinc(II)].
作者信息
Hu Meihong, Zhang Shishen
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2009 Jul 22;65(Pt 8):m970. doi: 10.1107/S1600536809027044.
Abstract
In the crystal structure of the centrosymmetric title compound, [Zn(2)Cl(4)(C(14)H(14)N(4))(2)], the Zn(II) atom is coordinated by two N atoms from two 1,2-bis-(imidazol-1-ylmeth-yl)benzene ligands and two Cl atoms to confer a distorted tetra-hedral geometry at the metal center.
摘要
在中心对称的标题化合物[Zn₂Cl₄(C₁₄H₁₄N₄)₂]的晶体结构中，Zn(II)原子由来自两个1,2-双（咪唑-1-基甲基）苯配体的两个N原子和两个Cl原子配位，在金属中心形成扭曲的四面体几何构型。
相似文献
1
Bis[μ(2)-1,2-bis-(imidazol-1-ylmeth-yl)benzene-κN:N]bis-[dichloridozinc(II)].
Acta Crystallogr Sect E Struct Rep Online. 2009 Jul 22;65(Pt 8):m970. doi: 10.1107/S1600536809027044.
2
Poly[[μ(2)-1,2-bis-(1H-imidazol-1-ylmeth-yl)benzene-κN:N](μ(2)-tereph-thalato-κO:O)zinc(II)].
Acta Crystallogr Sect E Struct Rep Online. 2010 Oct 23;66(Pt 11):m1456. doi: 10.1107/S1600536810042406.
3
Poly[bis-[μ-1,4-bis-(imidazol-1-ylmeth-yl)benzene]-dichloridomanganese(II)].
Acta Crystallogr Sect E Struct Rep Online. 2011 Aug 1;67(Pt 8):m1156. doi: 10.1107/S1600536811029485. Epub 2011 Jul 30.
4
Poly[aqua[μ(2)-1,2-bis-(imidazol-1-yl-methyl)benzene-κN:N](μ(2)-5-bromo-benzene-1,3-dicarboxyl-ato-κO,O:O)nickel(II)].
Acta Crystallogr Sect E Struct Rep Online. 2009 May 7;65(Pt 6):m623. doi: 10.1107/S1600536809016286.
5
Bis{μ-1,3-bis-[(benzimidazol-1-yl)meth-yl]benzene-κN:N}bis-[dichloridozinc(II)] dimethyl-formamide disolvate.
Acta Crystallogr Sect E Struct Rep Online. 2009 May 7;65(Pt 6):m613. doi: 10.1107/S1600536809015943.
6
catena-Poly[[dichloridozinc(II)]-μ-1,4-bis-(1H-imidazol-1-yl)benzene].
Acta Crystallogr Sect E Struct Rep Online. 2010 Nov 6;66(Pt 12):m1518. doi: 10.1107/S1600536810044429.
7
Poly[(μ(2)-benzene-1,3-dicarboxyl-ato-κ(2)O(1):O(3)){μ(2)-1,2-bis-[(1H-imidazol-1-yl)meth-yl]benzene-κ(2)N(3):N(3')}zinc].
Acta Crystallogr Sect E Struct Rep Online. 2012 Jun 1;68(Pt 6):m826. doi: 10.1107/S1600536812022544. Epub 2012 May 26.
8
catena-Poly[[zinc(II)-bis-[μ-1,3-bis-(imidazol-1-ylmeth-yl)benzene-κN:N]] dinitrate methanol solvate].
Acta Crystallogr Sect E Struct Rep Online. 2009 Oct 10;65(Pt 11):m1326-7. doi: 10.1107/S1600536809040203.
9
Poly[bis-[μ-1,4-bis-(imidazol-1-ylmeth-yl)benzene]dichloridocadmium(II)].
Acta Crystallogr Sect E Struct Rep Online. 2008 Jun 28;64(Pt 7):m973. doi: 10.1107/S1600536808018990.
10
{1,2-Bis[(3,5-dimethyl-1H-pyrazol-1-yl-κN)meth-yl]benzene}-dichloridozinc(II).
Acta Crystallogr Sect E Struct Rep Online. 2011 Dec 1;67(Pt 12):m1715-6. doi: 10.1107/S1600536811046368. Epub 2011 Nov 9.
本文引用的文献
1
A short history of SHELX.
Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22. doi: 10.1107/S0108767307043930. Epub 2007 Dec 21.
2
Syntheses and characterization of six coordination polymers of zinc(II) and cobalt(II) with 1,3,5-benzenetricarboxylate anion and bis(imidazole) ligands.
Inorg Chem. 2007 Apr 16;46(8):3027-37. doi: 10.1021/ic061575l. Epub 2007 Mar 15.
3
New zinc phosphates decorated by imidazole-containing ligands.
Inorg Chem. 2005 Feb 7;44(3):552-8. doi: 10.1021/ic0487528.
4
A new type of entanglement involving one-dimensional ribbons of rings catenated to a three-dimensional network in the nanoporous structure of [Co(bix)2(H2O)2](SO4).7H2O [bix = 1,4-bis(imidazol-1-ylmethyl)benzene].
Chem Commun (Camb). 2004 Feb 21(4):380-1. doi: 10.1039/b314322h. Epub 2004 Jan 20.
5
From molecules to crystal engineering: supramolecular isomerism and polymorphism in network solids.
Chem Rev. 2001 Jun;101(6):1629-58. doi: 10.1021/cr9900432.
Zotero 插件