Bromido{dicyclo-hexyl[2'-(dimethyl-amino)biphenyl-2-yl]phosphine-κP}[2-(4,6-dimethyl-pyrimidin-2-yl)ferrocenyl-κC,N]palladium(II) dichloro-methane solvate.
作者信息
Hao Xin-Qi, Li Hong-Mei, Jiang Hui, Ma Yong-Tao, Song Mao-Ping
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2009 Apr 18;65(Pt 5):m529-30. doi: 10.1107/S1600536809012884.
Abstract
In the title compound, [FePdBr(C(5)H(5))(C(11)H(10)N(2))(C(26)H(36)NP)]·CH(2)Cl(2), the Pd atom displays a distorted square-planar coordination environment. The five-membered metallacycle adopts an envelope conformation with the coordinated cyclo-penta-dienyl C atom 0.4222 (4) Å out of plane. The dihedral angle between the pyrimidinyl ring and substituted cyclo-penta-dienyl ring is 21.47 (2)°. In the crystal structure, the dimeric unit is generated through the C-H⋯π contact via a crystallographic inversion centre, while the C-H⋯Cl contacts in the dimeric centre link the dichlormethane mol-ecules with the Pd complex mol-ecules.
摘要
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