[2,6-双(4,5-二氢-1H-咪唑-2-基)吡啶]二氯化锰(II)
[2,6-Bis(4,5-dihydro-1H-imidazol-2-yl)pyridine]dichloridomanganese(II).
作者信息
Ren Chun-Xia, Li Su-Yun, Yin Zhao-Zhong, Lu Xiang, Ding Yu-Qiang
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2009 Apr 25;65(Pt 5):m572-3. doi: 10.1107/S1600536809014354.
In the title compound, [MnCl(2)(C(11)H(13)N(5))], the Mn(II) ion is five-coordinated in a distorted square-pyramidal geometry, with three N atoms from the neutral tridentate 2,6-bis-(4,5-dihydro-1H-imidazol-2-yl)pyridine ligand and one chloride ion forming the basal plane and the other chloride ion in the apical position. Both dihydro-imidazole rings adopt envelope conformations. In the crystal structure, mol-ecules are linked into a three-dimensional network by N-H⋯Cl and C-H⋯Cl hydrogen bonds.
在标题化合物[MnCl₂(C₁₁H₁₃N₅)]中，Mn(II)离子以扭曲的四方锥几何构型五配位，来自中性三齿2,6-双-(4,5-二氢-1H-咪唑-2-基)吡啶配体的三个N原子和一个氯离子形成基面，另一个氯离子处于顶端位置。两个二氢咪唑环均采用信封式构象。在晶体结构中，分子通过N—H⋯Cl和C—H⋯Cl氢键连接成三维网络。
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