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[2,6-双(4,5-二氢-1H-咪唑-2-基)吡啶]二氯化锰(II)

[2,6-Bis(4,5-dihydro-1H-imidazol-2-yl)pyridine]dichloridomanganese(II).

作者信息

Ren Chun-Xia, Li Su-Yun, Yin Zhao-Zhong, Lu Xiang, Ding Yu-Qiang

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2009 Apr 25;65(Pt 5):m572-3. doi: 10.1107/S1600536809014354.

DOI:10.1107/S1600536809014354
PMID:21583801
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2977615/
Abstract

In the title compound, [MnCl(2)(C(11)H(13)N(5))], the Mn(II) ion is five-coordinated in a distorted square-pyramidal geometry, with three N atoms from the neutral tridentate 2,6-bis-(4,5-dihydro-1H-imidazol-2-yl)pyridine ligand and one chloride ion forming the basal plane and the other chloride ion in the apical position. Both dihydro-imidazole rings adopt envelope conformations. In the crystal structure, mol-ecules are linked into a three-dimensional network by N-H⋯Cl and C-H⋯Cl hydrogen bonds.

摘要

在标题化合物[MnCl₂(C₁₁H₁₃N₅)]中，Mn(II)离子以扭曲的四方锥几何构型五配位，来自中性三齿2,6-双-(4,5-二氢-1H-咪唑-2-基)吡啶配体的三个N原子和一个氯离子形成基面，另一个氯离子处于顶端位置。两个二氢咪唑环均采用信封式构象。在晶体结构中，分子通过N—H⋯Cl和C—H⋯Cl氢键连接成三维网络。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/492b/2977615/4c3ad7f5db28/e-65-0m572-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/492b/2977615/20014cf276eb/e-65-0m572-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/492b/2977615/4c3ad7f5db28/e-65-0m572-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/492b/2977615/20014cf276eb/e-65-0m572-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/492b/2977615/4c3ad7f5db28/e-65-0m572-fig2.jpg

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