二氯{2-吗啉代-N-[1-(2-吡啶基)亚乙基]乙胺-κN,N',N''}锰(II)
Dichlorido{2-morpholino-N-[1-(2-pyrid-yl)ethyl-idene]ethanamine-κN,N',N''}manganese(II).
作者信息
Ikmal Hisham Nurul Azimah, Suleiman Gwaram Nura, Khaledi Hamid, Mohd Ali Hapipah
机构信息
Department of Chemistry, University of Malaya, 50603 Kuala Lumpur, Malaysia.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2010 Dec 4;67(Pt 1):m41. doi: 10.1107/S1600536810050221.
In the title compound, [MnCl(2)(C(13)H(19)N(3)O)], the Mn(II) ion is penta-coordinated in a distorted square-pyramidal geometry. The coordination environment is defined by the N,N',N''-tridentate Schiff base ligand and one Cl atom in the basal positions and one Cl atom in the apical position. In the crystal, inter-molecular C-H⋯Cl hydrogen bonds link the mol-ecules into a three-dimensional network. An intra-molecular C-H⋯Cl hydrogen bond is also observed.
在标题化合物[MnCl₂(C₁₃H₁₉N₃O)]中，Mn(II)离子以扭曲的四方锥几何构型进行五配位。配位环境由位于基面位置的N,N',N''-三齿席夫碱配体和一个Cl原子以及位于顶点位置的一个Cl原子确定。在晶体中，分子间的C—H⋯Cl氢键将分子连接成三维网络。还观察到一个分子内的C—H⋯Cl氢键。
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