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[2,6-Bis(6-methyl-quinolin-2-yl)pyridine-κN,N',N'']dichloridomanganese(II).

作者信息

Li Xiao-Ping, Zhao Jian-She, Ng Seik Weng

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2010 Sep 25;66(Pt 10):m1298. doi: 10.1107/S1600536810037037.

Abstract

In the mol-ecule of the title compound, [MnCl(2)(C(25)H(19)N(3))], the three N atoms span the axial-equatorial-axial sites of the trigonal-bipyramidal coordination polyhedron; the geometry of the Mn(II) atom is 34% distorted from trigonal-bipyramidal (towards square-pyramidal along the Berry pseudorotation pathway). One of the Cl atoms is disordered over two positions in a 0.82 (3):0.18 (3) ratio. Weak inter-molecular C-H⋯Cl hydrogen bonding occurs in the crystal structure.

摘要
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2c6a/2983179/52328fe1d2d9/e-66-m1298-fig1.jpg

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