Hagrman PJ, Hagrman D, Zubieta J
Department of Chemistry, Syracuse University, Syracuse, New York 13244 (USA).
Angew Chem Int Ed Engl. 1999 Sep;38(18):2638-2684. doi: 10.1002/(sici)1521-3773(19990917)38:18<2638::aid-anie2638>3.0.co;2-4.
A blueprint for the design of oxide materials is provided by nature. By borrowing from nature's ability to influence inorganic microstructures in biomineralization processes and in the hydrothermal synthesis of complex minerals, a new class of materials in which organic components exert a role in controlling inorganic microstructure is evolving. By employing members of the ever-expanding class of polymeric coordination complex cations, novel molybdenum oxide substructures, such as the one shown, may be prepared.
自然界为氧化物材料的设计提供了蓝图。通过借鉴自然界在生物矿化过程和复杂矿物水热合成中影响无机微观结构的能力，一类新的材料正在不断发展，在这类材料中有机成分在控制无机微观结构方面发挥作用。通过使用不断扩大的聚合配位复合阳离子类别中的成员，可以制备出如图所示的新型氧化钼亚结构。
