1-（2-氟苄叉亚氨基）吡啶双（1,2-二氰基乙烯-1,2-二硫醇合）镍（II）
1-(2-Fluoro-benzyl-ideneamino)pyridinium bis-(1,2-dicyano-ethene-1,2-dithiol-ato)nickelate(II).
作者信息
Zhang Hui, Zhou Quan, Hu Fengkai, Xu Han, Chang Guanru
机构信息
Department of Chemistry, Huangshan University, Huangshang 245001, People's Republic of China.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2009 Apr 30;65(Pt 5):m599. doi: 10.1107/S1600536809015360.
Abstract
In the title complex, (C(12)H(10)FN(2))(2)[Ni(C(4)N(2)S(2))(2)], the anion lies on an inversion center with the Ni(II) ion coordinated by four S atoms in a slightly distorted square-planar environment. In the unique cation, the dihedral angle between the benzene and pyridine rings is 7.1 (2) Å.
摘要
在标题配合物（C₁₂H₁₀FN₂）₂[Ni（C₄N₂S₂）₂]中，阴离子位于一个对称中心上，Ni（II）离子在略微扭曲的平面正方形环境中由四个S原子配位。在独特的阳离子中，苯环和吡啶环之间的二面角为7.1（2）Å。
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