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亚磷酸二氢胞嘧啶中的氢键

Hydrogen bonding in cytosinium dihydrogen phosphite.

作者信息

Messai Amel, Benali-Cherif Nourredine, Jeanneau Erwann, Luneau Dominique

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2009 Apr 30;65(Pt 5):o1147-8. doi: 10.1107/S1600536809014020.

DOI:10.1107/S1600536809014020
PMID:21583952
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2977815/
Abstract

In the title compound, C(4)H(8)N(3)O(4)P(+)·H(2)PO(3) (-), the cytosine mol-ecule is monoprotonated and the phospho-ric acid is in the monoionized state. Strong hydrogen bonds, dominated by N-H⋯O inter-actions, are responsible for cohesion between the organic and inorganic layers and maintain the stability of this structure.

摘要

在标题化合物C(4)H(8)N(3)O(4)P(+)·H(2)PO(3) (-)中,胞嘧啶分子为单质子化,磷酸处于单离子化状态。以N-H⋯O相互作用为主导的强氢键负责有机层和无机层之间的凝聚,并维持该结构的稳定性。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e52b/2977815/35b1df09c6a4/e-65-o1147-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e52b/2977815/3984a3dd64d6/e-65-o1147-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e52b/2977815/35b1df09c6a4/e-65-o1147-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e52b/2977815/3984a3dd64d6/e-65-o1147-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e52b/2977815/35b1df09c6a4/e-65-o1147-fig2.jpg

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本文引用的文献

1
Creatinium perchlorate.高氯酸肌胺
Acta Crystallogr Sect E Struct Rep Online. 2009 Feb 4;65(Pt 3):o460. doi: 10.1107/S1600536809003171.
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Structure validation in chemical crystallography.化学晶体学中的结构验证
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Electrostatic properties of cytosine monohydrate from diffraction data.
Acta Crystallogr B. 1990 Aug 1;46 ( Pt 4):532-8. doi: 10.1107/s0108768190001343.