Khemiri Hamed, Akriche Samah, Rzaigui Mohamed
Laboratoire de Chimie des Matériaux, Faculté des Sciences de Bizerte, 7021 Zarzouna Bizerte, Tunisia.
Acta Crystallogr Sect E Struct Rep Online. 2009 Apr 30;65(Pt 5):o1152. doi: 10.1107/S1600536809014536.
In the title compound, C(7)H(10)N(+)·H(2)PO(4) (-)·H(3)PO(4), there is a clear distinction between the P-O/P=O and P-OH bond lengths. In the crystal, the H(2)PO(4) (-) anions and H(3)PO(4) mol-ecules are linked by O-H⋯O hydrogen bonds, leading to layers propagating in the bc plane. The organic cations are located between these layers and inter-act with them by way of N-H⋯O hydrogen bonds.
在标题化合物C₇H₁₀N⁺·H₂PO₄⁻·H₃PO₄中，P - O/P = O键长与P - OH键长之间存在明显差异。在晶体中，H₂PO₄⁻阴离子和H₃PO₄分子通过O - H⋯O氢键相连，形成在bc平面扩展的层状结构。有机阳离子位于这些层之间，并通过N - H⋯O氢键与它们相互作用。
