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磷酸二氢2-苯基苯胺盐

2-Phenyl-anilinium dihydrogen phosphate.

作者信息

Mrad Mohamed Lahbib, Ammar Salah, Ferretti Valeria, Rzaigui Mohamed, Ben Nasr Cherif

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2010 Sep 11;66(Pt 10):o2556. doi: 10.1107/S160053681003535X.

DOI:10.1107/S160053681003535X
PMID:21587543
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2983432/
Abstract

In the crystal structure of the title compound, C(12)H(12)N(+)·H(2)PO(4) (-), the dihydrogen phosphate anions and the 2-phenyl-anilinium cations are associated via O-H⋯O and N-H⋯O hydrogen bonds so as to build inorganic layers around the x = 1/2 plane. The organic entities are anchored between these layers through C-H⋯O hydrogen bonds, forming a three-dimensional infinite network. The dihedral angle between the aromatic rings is 44.7 (4)°.

摘要

在标题化合物C(12)H(12)N⁺·H₂PO₄⁻的晶体结构中，磷酸二氢根阴离子和2-苯基苯胺阳离子通过O-H⋯O和N-H⋯O氢键相互关联，从而在x = 1/2平面周围构建无机层。有机实体通过C-H⋯O氢键锚定在这些层之间，形成三维无限网络。芳环之间的二面角为44.7 (4)°。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/cb41/2983432/2ce754b37b3f/e-66-o2556-fig3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/cb41/2983432/0fb9588de569/e-66-o2556-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/cb41/2983432/7863e3dbd66c/e-66-o2556-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/cb41/2983432/2ce754b37b3f/e-66-o2556-fig3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/cb41/2983432/0fb9588de569/e-66-o2556-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/cb41/2983432/7863e3dbd66c/e-66-o2556-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/cb41/2983432/2ce754b37b3f/e-66-o2556-fig3.jpg

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本文引用的文献

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