二水合双-{3-[4-(1H-咪唑-1-基)苯基]-5-(吡啶-2-基-κN)-1H-1,2,4-三唑-1-基-κN(1)}锌
Diaqua-bis-{3-[4-(1H-imidazol-1-yl)phenyl]-5-(pyridin-2-yl-κN)-1H-1,2,4-triazol-1-ido-κN(1)}zinc.
作者信息
Wang You-Song, Qiu Guang-Mei, Wang Cui-Juan
机构信息
Department of Chemistry and Chemical Engineering, College of Life Science and Bioengineering, SouthWest JiaoTong University, Chengdu, Sichuan 610031, People's Republic of China.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2012 Sep 1;68(Pt 9):m1182-3. doi: 10.1107/S1600536812035428. Epub 2012 Aug 23.
The centrosymmetric mol-ecule of the title compound, [Zn(C(16)H(11)N(6))(2)(H(2)O)(2)], contains one Zn(2+) ion located on a center of symmetry, two 3-[4-(1H-imidazol-1-yl)phen-yl]-5-(pyridin-2-yl)-1H-1,2,4-triazol-1-ide (Ippyt) ligands and two coordinating water mol-ecules. The Zn(II) ion is six-coordinated in a distorted octa-hedral coordination geometry by four N atoms from two Ippyt ligands and by two O atoms from two water mol-ecules. Adjacent units are inter-connected though O-H⋯N hydrogen bonds, forming a three-dimensional network.
标题化合物[Zn(C₁₆H₁₁N₆)₂(H₂O)₂]的中心对称分子包含一个位于对称中心的Zn²⁺离子、两个3-[4-(1H-咪唑-1-基)苯基]-5-(吡啶-2-基)-1H-1,2,4-三唑-1-负离子（Ippyt）配体和两个配位水分子。Zn(II)离子通过来自两个Ippyt配体的四个N原子和来自两个水分子的两个O原子以扭曲的八面体配位几何构型进行六配位。相邻单元通过O—H⋯N氢键相互连接，形成三维网络。
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