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{Bis[2-(3,5-dimethyl-pyrazol-1-yl-κN)eth-yl]amine-κN}chloridopalladium(II) chloride 0.25-hydrate.

作者信息

Guzei Ilia A, Spencer Lara C, Miti Nangamso, Darkwa James

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2010 Sep 11;66(Pt 10):m1243. doi: 10.1107/S1600536810035427.

DOI:10.1107/S1600536810035427
PMID:21587393
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2983137/
Abstract

The title compound, [PdCl(C(14)H(23)N(5))]Cl·0.25H(2)O, is a pseudopolymorph of the previously reported compound [PdCl(C(14)H(23)N(5))]Cl·2H(2)O [de Mendoza et al. (2006 ▶). Acta Cryst. E62, m2934-m2936]. The cationic complex and chloride anion are disordered over two positions each in a 0.584 (4):0.416 (4) ratio. The geometry about the Pd atom is distorted square-planar. The pyrazole rings are almost perpendicular, forming a dihedral angle of 86.6 (6)° to each other, to mitigate steric conflict between their methyl groups.

摘要
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1e35/2983137/428e5d2fdce9/e-66-m1243-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1e35/2983137/428e5d2fdce9/e-66-m1243-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1e35/2983137/428e5d2fdce9/e-66-m1243-fig1.jpg

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引用本文的文献

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Acta Crystallogr E Crystallogr Commun. 2015 Mar 21;71(Pt 4):m98-9. doi: 10.1107/S2056989015005307. eCollection 2015 Apr 1.
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Coordination of bis-(pyrazol-1-yl)amine to palladium(II): influence of the co-ligands and counter-ions on the mol-ecular and crystal structures.双（吡唑-1-基）胺与钯（II）的配位：共配体和抗衡离子对分子结构和晶体结构的影响。
Acta Crystallogr E Crystallogr Commun. 2015 Jan 1;71(Pt 1):22-7. doi: 10.1107/S205698901402595X.

本文引用的文献

1
Highly efficient palladium precatalysts of homoscorpionate bispyrazolyl ligands for the more challenging Suzuki-Miyaura cross-coupling of aryl chlorides.高活性的同螯合双吡唑基配体钯前催化剂在更具挑战性的芳基氯的 Suzuki-Miyaura 交叉偶联反应中的应用。
Dalton Trans. 2010 Aug 21;39(31):7353-63. doi: 10.1039/c003174g. Epub 2010 Jul 6.
2
A short history of SHELX.SHELX简史。
Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22. doi: 10.1107/S0108767307043930. Epub 2007 Dec 21.
3
Retrieval of crystallographically-derived molecular geometry information.
晶体学衍生分子几何信息的检索。
J Chem Inf Comput Sci. 2004 Nov-Dec;44(6):2133-44. doi: 10.1021/ci049780b.
4
The Cambridge Structural Database: a quarter of a million crystal structures and rising.剑桥结构数据库：拥有二十五万个晶体结构且数量不断增加。
Acta Crystallogr B. 2002 Jun;58(Pt 3 Pt 1):380-8. doi: 10.1107/s0108768102003890. Epub 2002 May 29.